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Discrete Quadruple Stacks Formed in a Nanosized Metallorectangle
dc.contributor.author | Ibáñez, Susana | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2024-08-30T11:56:12Z | |
dc.date.available | 2024-08-30T11:56:12Z | |
dc.date.issued | 2024-08-10 | |
dc.identifier.citation | IBÁÑEZ, Susana; PERIS, Eduardo. Discrete Quadruple Stacks Formed in a Nanosized Metallorectangle. Inorganic Chemistry, 2024, 63, 34, 16070–16074. | ca_CA |
dc.identifier.issn | 0020-1669 | |
dc.identifier.uri | http://hdl.handle.net/10234/208801 | |
dc.description.abstract | An iridium-cornered nanosized metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and 4,4′-bipyridine. This metallorectangle was used as host for a series of planar molecules, including pyrene, triphenylene, perylene, coronene, and N,N′-dimethyl-naphthalenetetracarboxy-diimide (NTCDI). The binding of coronene and NTCDI followed a strongly positive cooperative 1:2 stoichiometric binding model, as the inclusion of the first guest generates the geometrical requirements for the optimum encapsulation of the second planar molecule. The simultaneous encapsulation of coronene and NTCDI produces a heteroguest inclusion system, whose exchange dynamics was studied by means of variable temperature 1H NMR spectroscopy. | ca_CA |
dc.description.sponsorShip | Funding for open access charge: CRUE-Universitat Jaume I | |
dc.format.extent | 5 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.relation.isPartOf | Inorganic Chemistry 2024, 63, 34. | ca_CA |
dc.rights | © 2024 The Authors. Published by American Chemical Society | ca_CA |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | ca_CA |
dc.subject | Aromatic compounds | ca_CA |
dc.subject | Cavities | ca_CA |
dc.subject | Encapsulation | ca_CA |
dc.subject | Hydrocarbons | ca_CA |
dc.subject | Ligands | ca_CA |
dc.subject | Binding models | ca_CA |
dc.subject | Bipyridines | ca_CA |
dc.subject | Coronene | ca_CA |
dc.subject | Exchange dynamics | ca_CA |
dc.subject | Imidazolylidene | ca_CA |
dc.subject | Perylenes | ca_CA |
dc.subject | Planar molecules | ca_CA |
dc.subject | Stoichiometric binding | ca_CA |
dc.subject | Triphenylenes | ca_CA |
dc.subject | Diimide | ca_CA |
dc.title | Discrete Quadruple Stacks Formed in a Nanosized Metallorectangle | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | 10.1021/acs.inorgchem.4c02653 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://pubs.acs.org/doi/full/10.1021/acs.inorgchem.4c02653 | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.name | Conselleria de Innovación, Universidades, Ciencia y Sociedad Digital, Generalitat Valenciana | ca_CA |
project.funder.name | Generalitat Valenciana | ca_CA |
oaire.awardNumber | PID2021-127862NB-I00 | ca_CA |
oaire.awardNumber | CIPROM/2021/079 | ca_CA |
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