Discrete Quadruple Stacks Formed in a Nanosized Metallorectangle
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Títol
Discrete Quadruple Stacks Formed in a Nanosized MetallorectangleData de publicació
2024-08-10Editor
American Chemical SocietyISSN
0020-1669Cita bibliogràfica
IBÁÑEZ, Susana; PERIS, Eduardo. Discrete Quadruple Stacks Formed in a Nanosized Metallorectangle. Inorganic Chemistry, 2024, 63, 34, 16070–16074.Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
https://pubs.acs.org/doi/full/10.1021/acs.inorgchem.4c02653Versió
info:eu-repo/semantics/publishedVersionParaules clau / Matèries
Resum
An iridium-cornered nanosized metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and 4,4′-bipyridine. This metallorectangle was used as host for a ... [+]
An iridium-cornered nanosized metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and 4,4′-bipyridine. This metallorectangle was used as host for a series of planar molecules, including pyrene, triphenylene, perylene, coronene, and N,N′-dimethyl-naphthalenetetracarboxy-diimide (NTCDI). The binding of coronene and NTCDI followed a strongly positive cooperative 1:2 stoichiometric binding model, as the inclusion of the first guest generates the geometrical requirements for the optimum encapsulation of the second planar molecule. The simultaneous encapsulation of coronene and NTCDI produces a heteroguest inclusion system, whose exchange dynamics was studied by means of variable temperature 1H NMR spectroscopy. [-]
Publicat a
Inorganic Chemistry 2024, 63, 34.Entitat finançadora
Conselleria de Innovación, Universidades, Ciencia y Sociedad Digital, Generalitat Valenciana | Generalitat Valenciana
Codi del projecte o subvenció
PID2021-127862NB-I00 | CIPROM/2021/079
Drets d'accés
© 2024 The Authors. Published by American Chemical Society
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
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