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Engineered Immobilised Organocatalysts for the Synthesis of Chiral Amines
dc.contributor.author | Maciá, María | |
dc.contributor.author | Muñoz, Iván | |
dc.contributor.author | Porcar, Raúl | |
dc.contributor.author | Cirujano, Francisco | |
dc.contributor.author | Altava, Belen | |
dc.contributor.author | Luis, Santiago V. | |
dc.contributor.author | Garcia-Verdugo, Eduardo | |
dc.date.accessioned | 2024-08-02T05:59:06Z | |
dc.date.available | 2024-08-02T05:59:06Z | |
dc.date.issued | 2024-02-20 | |
dc.identifier.citation | M. Maciá, I. Muñoz, R. Porcar, F. G. Cirujano, B. Altava, S. V. Luis, E. García-Verdugo, Adv. Synth. Catal. 2024, 366, 892. https://doi.org/10.1002/adsc.202301221 | ca_CA |
dc.identifier.issn | 1615-4150 | |
dc.identifier.issn | 1615-4169 | |
dc.identifier.uri | http://hdl.handle.net/10234/208447 | |
dc.description.abstract | The art of tuning functional polymeric materials through the covalent incorporation of organocatalysts lies at the core of creating asymmetric immobilized chiral catalysts that mimic the enzymatic action. Herein, we explore diverse synthetic techniques to immobilize l-proline-derived N-carbonyl amides on functional polymeric matrices, transforming them into chiral Lewis bases for facilitating the asymmetric reduction of ketimines with HSiCl3. A comprehensive examination of the design factors, encompassing linker selection, anions, and polymeric support characteristics, enables precise adjustment of steric and electronic features in these immobilized catalysts. This approach establishes structure-performance relationships, ultimately enabling the development of an engineered immobilized organocatalytic system that meets the desired criteria for activity, stability, and selectivity. | ca_CA |
dc.format.extent | 8 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.relation | Nuevas Herramientas en Química Verde para el Desarrollo de Procesos (Bio)Catalíticos Sostenibles de Valorización del Co2 y la Obtención Compuestos de Alto Valor Añadido | ca_CA |
dc.relation.isPartOf | Advanced Synthesis & Catalysis, 2024, vol. 366, no 4 | ca_CA |
dc.rights | © 2024 The Authors. Advanced Synthesis & Catalysis published by Wiley-VCH GmbH. This is an open access article under theterms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in anymedium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made. | ca_CA |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | ca_CA |
dc.subject | organocatalysis | ca_CA |
dc.subject | imine reduction | ca_CA |
dc.subject | immobilized catalyst | ca_CA |
dc.subject | continuous flow | ca_CA |
dc.subject | asymmetric catalysis | ca_CA |
dc.title | Engineered Immobilised Organocatalysts for the Synthesis of Chiral Amines | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1002/adsc.202301221 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.202301221 | ca_CA |
dc.description.sponsorship | This research was funded by Universitat Jaume I, grant number UJI-B2021-31; Consellería de Innovació, Universitat, i Ciencia, grant number AICO/2021/139; Ministerio de Ciencia e Innovación/Agencia Estatal de Investigación, MCIN/AEI/10.13039/501100011033 and ERDF A way of making Europe, grant number PDI2021-124695OB-C22. Technical support from the SCIC of the UJI is gratefully acknowledged. F. G. C. acknowledge the “Ramon y Cajal” contract with code RYC2020-028681-I MCIN/AEI/10.13039/501100011033 and by “ESF investing in your future”, | |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.identifier | http://dx.doi.org/10.13039/501100011033 | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
project.funder.name | Ministerio de Ciencia e Innovación | ca_CA |
oaire.awardNumber | UJI-B2021-31 | ca_CA |
oaire.awardNumber | MCIN/PEICTI2021-2023/PID2021-124695OB-C22 | ca_CA |
oaire.awardNumber | RYC2020-028681-I | ca_CA |
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Excepto si se señala otra cosa, la licencia del ítem se describe como: © 2024 The Authors. Advanced Synthesis & Catalysis published by Wiley-VCH GmbH. This is an open access article under theterms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in anymedium, provided the original work is properly cited, the use is non-commercial and no modifications or adaptations are made.