Engineered Immobilised Organocatalysts for the Synthesis of Chiral Amines
Impacto
Scholar |
Otros documentos de la autoría: Maciá, María; Muñoz, Iván; Porcar, Raúl; Cirujano, Francisco; Altava, Belen; Luis, Santiago V.; Garcia-Verdugo, Eduardo
Metadatos
Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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INVESTIGACIONMetadatos
Título
Engineered Immobilised Organocatalysts for the Synthesis of Chiral AminesAutoría
Fecha de publicación
2024-02-20Editor
WileyISSN
1615-4150; 1615-4169Cita bibliográfica
M. Maciá, I. Muñoz, R. Porcar, F. G. Cirujano, B. Altava, S. V. Luis, E. García-Verdugo, Adv. Synth. Catal. 2024, 366, 892. https://doi.org/10.1002/adsc.202301221Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://onlinelibrary.wiley.com/doi/full/10.1002/adsc.202301221Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
The art of tuning functional polymeric materials through the covalent incorporation of organocatalysts lies at the core of creating asymmetric immobilized chiral catalysts that mimic the enzymatic action. Herein, we ... [+]
The art of tuning functional polymeric materials through the covalent incorporation of organocatalysts lies at the core of creating asymmetric immobilized chiral catalysts that mimic the enzymatic action. Herein, we explore diverse synthetic techniques to immobilize l-proline-derived N-carbonyl amides on functional polymeric matrices, transforming them into chiral Lewis bases for facilitating the asymmetric reduction of ketimines with HSiCl3. A comprehensive examination of the design factors, encompassing linker selection, anions, and polymeric support characteristics, enables precise adjustment of steric and electronic features in these immobilized catalysts. This approach establishes structure-performance relationships, ultimately enabling the development of an engineered immobilized organocatalytic system that meets the desired criteria for activity, stability, and selectivity. [-]
Publicado en
Advanced Synthesis & Catalysis, 2024, vol. 366, no 4Entidad financiadora
Universitat Jaume I | Ministerio de Ciencia e Innovación
Identificador de la entidad financiadora
http://dx.doi.org/10.13039/501100011033
Código del proyecto o subvención
UJI-B2021-31 | MCIN/PEICTI2021-2023/PID2021-124695OB-C22 | RYC2020-028681-I
Título del proyecto o subvención
Nuevas Herramientas en Química Verde para el Desarrollo de Procesos (Bio)Catalíticos Sostenibles de Valorización del Co2 y la Obtención Compuestos de Alto Valor Añadido
Derechos de acceso
info:eu-repo/semantics/openAccess
Aparece en las colecciones
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