3D printed flow reactors for the synthesis of single crystal perovskites
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Other documents of the author: Iglesias, Diego; Tinajero Naranjo, Cristopher Alberto; Luis Gómez, Jaume; Aranda Alonso, Clara; Martinez Cuenca, Raul; Zanatta, Marcileia; Sans, Victor
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comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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Title
3D printed flow reactors for the synthesis of single crystal perovskitesAuthor (s)
Date
2024Publisher
ElsevierBibliographic citation
IGLESIAS, Diego, et al. 3D printed flow reactors for the synthesis of single crystal perovskites. Materials Today Energy, 2024, vol. 39, p. 101476.Type
info:eu-repo/semantics/articlePublisher version
https://www.sciencedirect.com/science/article/pii/S2468606923002320Version
info:eu-repo/semantics/publishedVersionSubject
Abstract
Defect-free single crystal perovskites have unique photophysical properties that makes them highly
attractive for a range of optoelectronic applications. However, their syntheses largely rely on batch
protocols, ... [+]
Defect-free single crystal perovskites have unique photophysical properties that makes them highly
attractive for a range of optoelectronic applications. However, their syntheses largely rely on batch
protocols, which are limited in terms of reproducibility and scalability. Here, a new methodology is
presented to develop tailored continuous-flow platforms for the synthesis of lead halide perovskites. The
digital design of the reactors and their manufacturing with 3D printing, employing commercially
available resins and low-cost stereolithography, was achieved. The reactor chamber was designed to
facilitate the continuous slow addition of reagents to the reaction chamber, thus maintaining a constant
concentration of reagents inside the reactor. The highly controlled synthetic conditions allowed for a
high reproducibility of the crystallization process, with yields ranging between 8 and 15% in weight in
eight consecutive reaction cycles. The crystals produced were characterized and demonstrated excellent
photoluminescence properties. [-]
Is part of
Materials Today Energy, 2024Funder Name
European Union's Horizon 2020 | Marie Skłodowska-Curie Individual Fellowships | Agencia Estatal de Investigación | Generalitat Valenciana | Universitat Jaume I | Ministerio de Universidades | Ministerio de Ciencia e Innovación | NextGeneration EU
Project code
PID2020-119628RB-C33 | MCIN/AEI/10.13039/501100011033 | CIDEGENT 2018/036 | CIGRIS/2021/075 | FPU21/03740 | TED2021-129758B-C33 | MCIN/AEI/10.13039/501100011033/European Union NextGeneration EU/PRTR
Investigation project
info:eu-repo/grantAgreement/EC/H2020/101026335Rights
2468-6069/© 2023 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY license
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
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