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A Sustainable Approach to Selective Hydrogenation of Unsaturated Esters and Aldehydes with Ruthenium Catalysts
dc.contributor.author | Passos, Lucas H. R. | |
dc.contributor.author | Martínez Agramunt, Víctor | |
dc.contributor.author | Gusev, Dmitry | |
dc.contributor.author | Peris, Eduardo | |
dc.contributor.author | dos Santos, Eduardo | |
dc.date.accessioned | 2023-06-20T07:19:48Z | |
dc.date.available | 2023-06-20T07:19:48Z | |
dc.date.issued | 2023-05-12 | |
dc.identifier.citation | PASSOS, Lucas HR, et al. A Sustainable Approach to Selective Hydrogenation of Unsaturated Esters and Aldehydes with Ruthenium Catalysts. ChemCatChem, 15, 12, e202300394. | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/202898 | |
dc.description.abstract | The reduction of esters and aldehydes to alcohols is an important reaction in the chemical industry to produce a wide range of bulk and fine chemicals. Herein, the unexpected behavior of three state-of-the-art, commercially available Ru-catalysts for the hydrogenation of these feedstocks is reported. For ester and aldehydes containing a C=C bond, it was possible to carry out the selective hydrogenation of the ester or aldehyde functionality while keeping the C=C double-bond essentially untouched. Furthermore, it is demonstrated that these substrates can be reduced under very mild reaction conditions (as low as 40 °C and 5 bar of H2) and that anisole, a solvent with a high sustainability rank, is suitable for these catalytic hydrogenations. | ca_CA |
dc.description.sponsorShip | Funding for open access charge: CRUE-Universitat Jaume I | |
dc.format.extent | 10 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.rights | © 2023 Wiley-VCH GmbH | ca_CA |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | ca_CA |
dc.subject | chemoselectivity | ca_CA |
dc.subject | homogeneous catalysis | ca_CA |
dc.subject | renewable feedstock | ca_CA |
dc.title | A Sustainable Approach to Selective Hydrogenation of Unsaturated Esters and Aldehydes with Ruthenium Catalysts | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1002/cctc.202300394 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.name | Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) | ca_CA |
project.funder.name | European Union (NextGenerationEU) | ca_CA |
project.funder.name | Universitat Jaume I | ca_CA |
project.funder.name | Minas Gerais State Agency for Research and Development (FAPEMIG) | ca_CA |
oaire.awardNumber | 140669/2020-5 | ca_CA |
oaire.awardNumber | MGS/2021/07 | ca_CA |
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