A Sustainable Approach to Selective Hydrogenation of Unsaturated Esters and Aldehydes with Ruthenium Catalysts
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Altres documents de l'autoria: Passos, Lucas H. R.; Martínez Agramunt, Víctor; Gusev, Dmitry; Peris, Eduardo; dos Santos, Eduardo
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Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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Títol
A Sustainable Approach to Selective Hydrogenation of Unsaturated Esters and Aldehydes with Ruthenium CatalystsAutoria
Data de publicació
2023-05-12Editor
WileyCita bibliogràfica
PASSOS, Lucas HR, et al. A Sustainable Approach to Selective Hydrogenation of Unsaturated Esters and Aldehydes with Ruthenium Catalysts. ChemCatChem, 15, 12, e202300394.Tipus de document
info:eu-repo/semantics/articleVersió
info:eu-repo/semantics/publishedVersionParaules clau / Matèries
Resum
The reduction of esters and aldehydes to alcohols is an important reaction in the chemical industry to produce a wide range of bulk and fine chemicals. Herein, the unexpected behavior of three state-of-the-art, ... [+]
The reduction of esters and aldehydes to alcohols is an important reaction in the chemical industry to produce a wide range of bulk and fine chemicals. Herein, the unexpected behavior of three state-of-the-art, commercially available Ru-catalysts for the hydrogenation of these feedstocks is reported. For ester and aldehydes containing a C=C bond, it was possible to carry out the selective hydrogenation of the ester or aldehyde functionality while keeping the C=C double-bond essentially untouched. Furthermore, it is demonstrated that these substrates can be reduced under very mild reaction conditions (as low as 40 °C and 5 bar of H2) and that anisole, a solvent with a high sustainability rank, is suitable for these catalytic hydrogenations. [-]
Entitat finançadora
Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) | European Union (NextGenerationEU) | Universitat Jaume I | Minas Gerais State Agency for Research and Development (FAPEMIG)
Codi del projecte o subvenció
140669/2020-5 | MGS/2021/07
Drets d'accés
© 2023 Wiley-VCH GmbH
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
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