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A redox-switchable catalyst with an 'unplugged' redox tag
dc.contributor.author | Gutiérrez Peña, Cristian Leonardo | |
dc.contributor.author | Poyatos, Macarena | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2022-11-08T14:35:10Z | |
dc.date.available | 2022-11-08T14:35:10Z | |
dc.date.issued | 2022-08-24 | |
dc.identifier.citation | GUTIÉRREZ-PEÑA, Cristian L.; POYATOS, Macarena; PERIS, Eduardo. A redox-switchable catalyst with an ‘unplugged’redox tag. Chemical Communications, 2022, vol. 58, no 75, p. 10564-10567. | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/200728 | |
dc.description.abstract | Two bis-(propyl-imidazolium)-napthalenediimide (NDI) salts were prepared and used as N-heterocyclic carbene (NHC) precursors for the preparation of dimetallic complexes of rhodium and iridium. Infrared spectroelectrochemical studies indicate that the metals are sensitive to changes in the electronic state of the NDI moiety. The catalytic behavior of the rhodium and iridium complexes was tested in the cycloisomerization of alkynoic acids, where the complexes showed effective redox-switching properties. | ca_CA |
dc.format.extent | 4 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Royal Society of Chemistry | ca_CA |
dc.relation.isPartOf | Chemical Communications, Volume 58, Issue 75, August 2022 | ca_CA |
dc.rights | This journal is © The Royal Society of Chemistry 2022 | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | ca_CA |
dc.subject | redox switching | ca_CA |
dc.subject | rhodium | ca_CA |
dc.subject | iridium | ca_CA |
dc.subject | catalyst | ca_CA |
dc.subject | switching properties | ca_CA |
dc.subject | alkynoic acids | ca_CA |
dc.title | A redox-switchable catalyst with an 'unplugged' redox tag | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | 10.1039/D2CC02497G | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
project.funder.name | Ministerio de Ciencia, Innovación y Universidades (Spain) | ca_CA |
project.funder.name | Serveis Centrals d’Instrumentació Científica (SCIC-UJI) | ca_CA |
project.funder.name | Santiago Grisolía Program | ca_CA |
oaire.awardNumber | PGC2018-093382-B-I00 | ca_CA |
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