A redox-switchable catalyst with an 'unplugged' redox tag
Impacte
![Google Scholar](/xmlui/themes/Mirage2/images/uji/logo_google.png)
![Microsoft Academico](/xmlui/themes/Mirage2/images/uji/logo_microsoft.png)
Metadades
Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
comunitat-uji-handle4:
INVESTIGACIONAquest recurs és restringit
10.1039/D2CC02497G |
Metadades
Títol
A redox-switchable catalyst with an 'unplugged' redox tagData de publicació
2022-08-24Editor
Royal Society of ChemistryCita bibliogràfica
GUTIÉRREZ-PEÑA, Cristian L.; POYATOS, Macarena; PERIS, Eduardo. A redox-switchable catalyst with an ‘unplugged’redox tag. Chemical Communications, 2022, vol. 58, no 75, p. 10564-10567.Tipus de document
info:eu-repo/semantics/articleVersió
info:eu-repo/semantics/publishedVersionParaules clau / Matèries
Resum
Two bis-(propyl-imidazolium)-napthalenediimide (NDI) salts were prepared and used as N-heterocyclic carbene (NHC) precursors for the preparation of dimetallic complexes of rhodium and iridium. Infrared spectroelectr ... [+]
Two bis-(propyl-imidazolium)-napthalenediimide (NDI) salts were prepared and used as N-heterocyclic carbene (NHC) precursors for the preparation of dimetallic complexes of rhodium and iridium. Infrared spectroelectrochemical studies indicate that the metals are sensitive to changes in the electronic state of the NDI moiety. The catalytic behavior of the rhodium and iridium complexes was tested in the cycloisomerization of alkynoic acids, where the complexes showed effective redox-switching properties. [-]
Publicat a
Chemical Communications, Volume 58, Issue 75, August 2022Entitat finançadora
Ministerio de Ciencia, Innovación y Universidades (Spain) | Serveis Centrals d’Instrumentació Científica (SCIC-UJI) | Santiago Grisolía Program
Codi del projecte o subvenció
PGC2018-093382-B-I00
Drets d'accés
This journal is © The Royal Society of Chemistry 2022
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/restrictedAccess
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/restrictedAccess
Apareix a les col.leccions
- INAM_Articles [521]