Synthesis of di-gold(I) metallotweezer
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Title
Synthesis of di-gold(I) metallotweezerAuthor (s)
Tutor/Supervisor; University.Department
Peris Fajarnés, Eduardo Víctor; Universitat Jaume I. Departament de Química Inorgànica i OrgànicaDate
2019-07Publisher
Universitat Jaume IAbstract
The aims of this current project in my passage through the Organometallic Chemistry
group and Homogeneous Catalysis research group, at the University Jaume I, were
divided in the following three:
To obtain the ... [+]
The aims of this current project in my passage through the Organometallic Chemistry
group and Homogeneous Catalysis research group, at the University Jaume I, were
divided in the following three:
To obtain the 2,6-Bis(3-ethynyl-5-tert-butylphenyl)pyridine, a ligand precursor
for the preparation of a new di-Au(I) metallotweezer. This compound is reported
in the literature, but we aim to improve its synthesis.
To synthetize the new metallotweezer based of the alkynyl fragment in 2,6-Bis(3-
ethynyl-5-tert-butylphenyl)pyridine, in combination with a N-heterocyclic
carbene ligand fused with a pyrene fragment.
To study this system for the recognition of organic substrates by exploiting the -
surface areas of the polyaromatic-adorned NHCs ligands. [-]
Description
Treball Final de Grau en Química. Codi: QU0943. Curs acadèmic: 2018/2019
Type
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- Grau en Química [265]