Self‐assembly and chiroptical properties in supramolecular complexes of adenosine phosphates and guanidinium‐bispyrene
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Other documents of the author: Trévisan, Marie; Fossépré, Mathieu; Paolantoni, Delphine; RUBIO-MAGNIETO, JENIFER; Dumy, Pascal; Ulrich, Sébastien; Surin, Mathieu
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comunitat-uji-handle3:10234/8639
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https://doi.org/10.1002/chir.22852 |
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Title
Self‐assembly and chiroptical properties in supramolecular complexes of adenosine phosphates and guanidinium‐bispyreneAuthor (s)
Date
2018-06Publisher
WileyISSN
0899-0042; 1520-636XBibliographic citation
TRÉVISAN, Marie, et al. Self‐assembly and chiroptical properties in supramolecular complexes of adenosine phosphates and guanidinium‐bispyrene. Chirality, 2018, vol. 30, no 6, p. 719-729Type
info:eu-repo/semantics/articlePublisher version
https://onlinelibrary.wiley.com/doi/full/10.1002/chir.22852Version
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Abstract
Supramolecular systems that respond to the hydrolysis of adenosine phosphates (APs) are attractive for biosensing and to fabricate bioinspired self‐assembled materials. Here, we report on the formation of supramolecular ... [+]
Supramolecular systems that respond to the hydrolysis of adenosine phosphates (APs) are attractive for biosensing and to fabricate bioinspired self‐assembled materials. Here, we report on the formation of supramolecular complexes between an achiral guanidinium derivative bearing two pyrene moieties, with each of the three adenosine phosphates: AMP, ADP, and ATP. By combining results from circular dichroism spectroscopy and molecular modeling simulations, we explore the induced chirality, the dynamics of the complexes, and the interactions at play, which altogether provide insights into the supramolecular self‐assembly between APs and the guanidinium‐bispyrene. Finally, we identify the chiroptical signals of interest in mixtures of the guanidinium derivative with the three APs in different proportions. This study constitutes a basis to evolve toward a chiroptical detection of the hydrolysis of APs based on organic supramolecular probes. [-]
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Chirality, 2018, vol. 30, no 6Rights
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