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Self‐assembly and chiroptical properties in supramolecular complexes of adenosine phosphates and guanidinium‐bispyrene
dc.contributor.author | Trévisan, Marie | |
dc.contributor.author | Fossépré, Mathieu | |
dc.contributor.author | Paolantoni, Delphine | |
dc.contributor.author | RUBIO-MAGNIETO, JENIFER | |
dc.contributor.author | Dumy, Pascal | |
dc.contributor.author | Ulrich, Sébastien | |
dc.contributor.author | Surin, Mathieu | |
dc.date.accessioned | 2019-02-27T07:48:08Z | |
dc.date.available | 2019-02-27T07:48:08Z | |
dc.date.issued | 2018-06 | |
dc.identifier.citation | TRÉVISAN, Marie, et al. Self‐assembly and chiroptical properties in supramolecular complexes of adenosine phosphates and guanidinium‐bispyrene. Chirality, 2018, vol. 30, no 6, p. 719-729 | ca_CA |
dc.identifier.issn | 0899-0042 | |
dc.identifier.issn | 1520-636X | |
dc.identifier.uri | http://hdl.handle.net/10234/181573 | |
dc.description.abstract | Supramolecular systems that respond to the hydrolysis of adenosine phosphates (APs) are attractive for biosensing and to fabricate bioinspired self‐assembled materials. Here, we report on the formation of supramolecular complexes between an achiral guanidinium derivative bearing two pyrene moieties, with each of the three adenosine phosphates: AMP, ADP, and ATP. By combining results from circular dichroism spectroscopy and molecular modeling simulations, we explore the induced chirality, the dynamics of the complexes, and the interactions at play, which altogether provide insights into the supramolecular self‐assembly between APs and the guanidinium‐bispyrene. Finally, we identify the chiroptical signals of interest in mixtures of the guanidinium derivative with the three APs in different proportions. This study constitutes a basis to evolve toward a chiroptical detection of the hydrolysis of APs based on organic supramolecular probes. | ca_CA |
dc.format.extent | 11 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.relation.isPartOf | Chirality, 2018, vol. 30, no 6 | ca_CA |
dc.rights | Copyright © John Wiley & Sons, Inc. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | adenosine phosphates | ca_CA |
dc.subject | ATP | ca_CA |
dc.subject | circular dichroism | ca_CA |
dc.subject | guanidinium | ca_CA |
dc.subject | molecular dynamics | ca_CA |
dc.subject | supramolecular self‐assembly | ca_CA |
dc.title | Self‐assembly and chiroptical properties in supramolecular complexes of adenosine phosphates and guanidinium‐bispyrene | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1002/chir.22852 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | https://onlinelibrary.wiley.com/doi/full/10.1002/chir.22852 | ca_CA |
dc.contributor.funder | Research in Mons was supported by the Fonds de la Recherche Scientifique—FNRS under the grants 1.B333.15F (CHIRNATES) and F.4532.16 (MIS‐SHERPA). Research in Montpellier was supported by the ANR (ANR‐11‐PDOC‐002‐02) and the LabEx CheMISyst (ANR‐10‐LABX‐05‐01). J.R.M., M.F., and M.S. are F.R.S.‐FNRS researchers. The authors thank COST Action CM1304 (Emergence and Evolution of Complex Chemical Systems) for the support of the collaboration | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
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