A rhodium(I)–oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions
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Otros documentos de la autoría: kleinhans, George; Guisado-Barrios, Gregorio; Liles, David C.; Bertrand, Guy; Bezuidenhout, Daniela
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Título
A rhodium(I)–oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactionsAutoría
Fecha de publicación
2016-01Editor
Royal Society of ChemistryCita bibliográfica
KLEINHANS, George, et al. A rhodium (I)–oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions. Chemical Communications, 2016, vol. 52, no 17, p. 3504-3507.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC00029K#!divAbstractResumen
An air-stable rhodium(I)–oxygen adduct featuring a CNC-pincer ligand, based on 1,2,3-triazol-5-ylidenes, catalyzes the homo-dimerization and hydrothiolation of alkynes, affording the gem-enyne and α-vinyl sulfide ... [+]
An air-stable rhodium(I)–oxygen adduct featuring a CNC-pincer ligand, based on 1,2,3-triazol-5-ylidenes, catalyzes the homo-dimerization and hydrothiolation of alkynes, affording the gem-enyne and α-vinyl sulfide isomers, respectively, with excellent selectivity. A one-pot stepwise strategy allows the selective catalytic preparation of non-symmetric bis-vinyl sulfides, as well as the alkyne dimerization-hydrothiolation tandem reactions. [-]
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Chemical Communications, 2016, vol. 52, no 17Derechos de acceso
info:eu-repo/semantics/restrictedAccess
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