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A rhodium(I)–oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions

dc.contributor.authorkleinhans, George
dc.contributor.authorGuisado-Barrios, Gregorio
dc.contributor.authorLiles, David C.
dc.contributor.authorBertrand, Guy
dc.contributor.authorBezuidenhout, Daniela
dc.date.accessioned2016-09-01T14:00:45Z
dc.date.available2016-09-01T14:00:45Z
dc.date.issued2016-01
dc.identifier.citationKLEINHANS, George, et al. A rhodium (I)–oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions. Chemical Communications, 2016, vol. 52, no 17, p. 3504-3507.ca_CA
dc.identifier.urihttp://hdl.handle.net/10234/162159
dc.description.abstractAn air-stable rhodium(I)–oxygen adduct featuring a CNC-pincer ligand, based on 1,2,3-triazol-5-ylidenes, catalyzes the homo-dimerization and hydrothiolation of alkynes, affording the gem-enyne and α-vinyl sulfide isomers, respectively, with excellent selectivity. A one-pot stepwise strategy allows the selective catalytic preparation of non-symmetric bis-vinyl sulfides, as well as the alkyne dimerization-hydrothiolation tandem reactions.ca_CA
dc.description.sponsorShipDIB gratefully acknowledges the National Research Foundation, South Africa (NRF 87890 and 92521), and Sasol Technology R&D Pty. Ltd, South Africa for financial support. GGB thanks the MINECO for a postdoctoral grant (FPDI-2013-16525) and Generalitat Valenciana for financial support (GV/2015/097). GB thanks the DOE (DEFG02-13ER16370) for financial support.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherRoyal Society of Chemistryca_CA
dc.relation.isPartOfChemical Communications, 2016, vol. 52, no 17ca_CA
dc.rightsCC0 1.0 Universal*
dc.rights.urihttp://creativecommons.org/publicdomain/zero/1.0/*
dc.subjectrhodiumca_CA
dc.subjectcatalystca_CA
dc.titleA rhodium(I)–oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactionsca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp:\\dx.doi.org/10.1039/C6CC00029K
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_CA
dc.relation.publisherVersionhttp://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC00029K#!divAbstractca_CA


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