A rhodium(I)–oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions
Impact
Scholar |
Other documents of the author: kleinhans, George; Guisado-Barrios, Gregorio; Liles, David C.; Bertrand, Guy; Bezuidenhout, Daniela
Metadata
Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
comunitat-uji-handle4:
INVESTIGACIONThis resource is restricted
http:\\dx.doi.org/10.1039/C6CC00029K |
Metadata
Title
A rhodium(I)–oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactionsAuthor (s)
Date
2016-01Publisher
Royal Society of ChemistryBibliographic citation
KLEINHANS, George, et al. A rhodium (I)–oxygen adduct as a selective catalyst for one-pot sequential alkyne dimerization-hydrothiolation tandem reactions. Chemical Communications, 2016, vol. 52, no 17, p. 3504-3507.Type
info:eu-repo/semantics/articleAbstract
An air-stable rhodium(I)–oxygen adduct featuring a CNC-pincer ligand, based on 1,2,3-triazol-5-ylidenes, catalyzes the homo-dimerization and hydrothiolation of alkynes, affording the gem-enyne and α-vinyl sulfide ... [+]
An air-stable rhodium(I)–oxygen adduct featuring a CNC-pincer ligand, based on 1,2,3-triazol-5-ylidenes, catalyzes the homo-dimerization and hydrothiolation of alkynes, affording the gem-enyne and α-vinyl sulfide isomers, respectively, with excellent selectivity. A one-pot stepwise strategy allows the selective catalytic preparation of non-symmetric bis-vinyl sulfides, as well as the alkyne dimerization-hydrothiolation tandem reactions. [-]
Is part of
Chemical Communications, 2016, vol. 52, no 17Rights
info:eu-repo/semantics/restrictedAccess
This item appears in the folowing collection(s)
- QUIO_Articles [701]
The following license files are associated with this item: