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Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†
dc.contributor.author | Pubill Ulldemolins, Cristina | |
dc.contributor.author | Poyatos, Macarena | |
dc.contributor.author | Bo, Carles | |
dc.contributor.author | Fernández, Elena | |
dc.date.accessioned | 2014-04-04T13:41:58Z | |
dc.date.available | 2014-04-04T13:41:58Z | |
dc.date.issued | 2013 | |
dc.identifier.uri | http://hdl.handle.net/10234/89436 | |
dc.description.abstract | In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to favour a less energetically demanding route towards the formation of diborated products versus allyl boronate esters. | ca_CA |
dc.format.extent | 6 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Royal Society of Chemistry | ca_CA |
dc.relation.isPartOf | Dalton Transactions. 2013, 42 | ca_CA |
dc.rights | © Royal Society of Chemistry 2014 | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Rhodium–NHC | ca_CA |
dc.title | Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation† | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1039/c2dt31659e | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://bs8lz6ys5q.search.serialssolutions.com/?ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info:sid/summon.serialssolutions.com&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Rhodium-NHC+complexes+mediate+diboration+versus+dehydrogenative+borylation+of+cyclic+olefins%3A+A+theoretical+explanation&rft.jtitle=Dalton+Transactions&rft.au=Pubill-Ulldemolins%2C+Cristina&rft.au=Poyatos%2C+MacArena&rft.au=Bo%2C+Carles&rft.au=Fern%C3%A1ndez%2C+Elena&rft.date=2013&rft.issn=1477-9226&rft.volume=42&rft.issue=3&rft.spage=746&rft.epage=752&rft.externalDBID=n%2Fa&rft.externalDocID=366294373¶mdict=ca | ca_CA |
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