Dual Catalysis with an IrIII–AuI Heterodimetallic Complex: Reduction of Nitroarenes by Transfer Hydrogenation using Primary Alcohols
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Otros documentos de la autoría: Sabater López, Sara; Peris, Eduardo; Mata Martínez, Jose A
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http://dx.doi.org/10.1002/chem.201103657 |
Metadatos
Título
Dual Catalysis with an IrIII–AuI Heterodimetallic Complex: Reduction of Nitroarenes by Transfer Hydrogenation using Primary AlcoholsFecha de publicación
2012-05Editor
WileyISSN
0947-6539Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://onlinelibrary.wiley.com/doi/10.1002/chem.201103657/fullPalabras clave / Materias
Resumen
A triazolyl-di-ylidene ligand has been used for the preparation of a homodimetallic complex of gold, and a heterodimetallic compound of gold and iridium. Both complexes have been fully characterized and their molecular ... [+]
A triazolyl-di-ylidene ligand has been used for the preparation of a homodimetallic complex of gold, and a heterodimetallic compound of gold and iridium. Both complexes have been fully characterized and their molecular structures have been determined by means of X-ray diffraction. The catalytic properties of these two complexes have been evaluated in the reduction of nitroarenes by transfer hydrogenation using primary alcohols. The two complexes afford different reaction products; whereas the AuI–AuI catalyst yields a hydroxylamine, the IrIII–AuI complex facilitates the formation of an imine. [-]
Publicado en
Chemistry - A European Journal, 2012, Vol. 18, num. 20Derechos de acceso
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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