Stereoselective synthesis of the cytotoxic macrolide aspergillide B

dc.contributor.author	Diaz-Oltra, Santiago
dc.contributor.author	Angulo-Pachón, César A.
dc.contributor.author	Kneeteman, María N.
dc.contributor.author	Murga, Juan
dc.contributor.author	Carda, Miguel
dc.contributor.author	Marco, J. Alberto
dc.date.accessioned	2012-08-07T09:55:53Z
dc.date.available	2012-08-07T09:55:53Z
dc.date.issued	2009
dc.identifier	http://dx.doi.org/10.1016/j.tetlet.2009.04.026
dc.identifier.citation	Tetrahedron Letters, 50, 27, p. 3783-3785
dc.identifier.issn	404039
dc.identifier.uri	http://hdl.handle.net/10234/43710
dc.description.abstract	A total, stereoselective synthesis of the cytotoxic macrolide aspergillide B has been performed. A cross metathesis and a C-glycosidation via a Mukaiyama-type aldol reaction were key features of the synthesis. The macrocyclic lactone ring was created by means of the Yamaguchi procedure. © 2009 Elsevier Ltd. All rights reserved.
dc.language.iso	eng
dc.publisher	Elsevier
dc.rights.uri	http://rightsstatements.org/vocab/CNE/1.0/	*
dc.subject	Aspergillides
dc.subject	Brown asymmetric allylation
dc.subject	Cross metathesis
dc.subject	Macrolides
dc.subject	Mukaiyama C-glycosidation
dc.subject	Yamaguchi macrolactonization
dc.title	Stereoselective synthesis of the cytotoxic macrolide aspergillide B
dc.type	info:eu-repo/semantics/article
dc.identifier.doi	http://dx.doi.org/10.1016/j.tetlet.2009.04.026
dc.rights.accessRights	info:eu-repo/semantics/restrictedAccess

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