Convergent, stereoselective syntheses of the glycosidase inhibitors broussonetines C, O and P
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Otros documentos de la autoría: Ribés Vidal, Celia; Falomir, Eva; Murga, Juan; Carda, Miguel; Marco, J. Alberto
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http://dx.doi.org/10.1016/j.tet.2009.10.066 |
Metadatos
Título
Convergent, stereoselective syntheses of the glycosidase inhibitors broussonetines C, O and PFecha de publicación
2009Editor
ElsevierISSN
404020Cita bibliográfica
Tetrahedron, 65, 51, p. 10612-10616Tipo de documento
info:eu-repo/semantics/articleResumen
The first syntheses of the polyhydroxylated alkaloids (iminosugars) broussonetines O and P, glycosidase inhibitors of the pyrrolidine class, have been performed in a convergent, stereocontrolled way from d-serine as ... [+]
The first syntheses of the polyhydroxylated alkaloids (iminosugars) broussonetines O and P, glycosidase inhibitors of the pyrrolidine class, have been performed in a convergent, stereocontrolled way from d-serine as the chiral starting material. The synthesis of broussonetin C, a further member of this compound family, is also reported. A cross-metathesis step was one key feature of the synthesis. The versatility of the synthetic concept chosen permits the access to many members of this compound family, both natural ones and analogues thereof. © 2009 Elsevier Ltd. All rights reserved. [-]
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