The role of the LATP particle size as a cornerstone of the cold sintering process
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Otros documentos de la autoría: Mormeneo-Segarra, Andrés; Ferrer Nicomedes, Sergio; Vicente-Agut, Nuria; Barba-Juan, Antonio
Metadatos
Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7033
comunitat-uji-handle3:10234/8618
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Título
The role of the LATP particle size as a cornerstone of the cold sintering processAutoría
Fecha de publicación
2024-02-13Editor
ElsevierISSN
0955-2219Cita bibliográfica
Mormeneo-Segarra, Andrés, et al. "The Role of the LATP particle size as a cornerstone of the Cold Sintering Process." Journal of the European Ceramic Society (2024).Tipo de documento
info:eu-repo/semantics/articleVersión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
An innovative sintering technique, the Cold Sintering Process (CSP), has been employed to obtain dense Li1.3Al0.3Ti1.7(PO4)3 (LATP) Solid-State Electrolytes (SSE) by optimising the particle size (d50) of the starting ... [+]
An innovative sintering technique, the Cold Sintering Process (CSP), has been employed to obtain dense Li1.3Al0.3Ti1.7(PO4)3 (LATP) Solid-State Electrolytes (SSE) by optimising the particle size (d50) of the starting powder. The CSP is carried out at 700 MPa, 150 ºC, and 90 min of sintering time, using acetic acid solution as Transient Liquid Phase (TLP). The CSP lowers the LATP sintering temperatures almost 1000 ºC. To study the electrical properties, an in operando Electrochemical Impedance Spectroscopy (EIS) technique has been used. The optimum d50 is 0.415 µm, yielding to competitive microstructure and electrical properties (ionic conductivity of 6.93·10−5 S cm−1 at 30 ºC, activation energy of 0.363 eV, and a relative density of 81.2 ± 0.8%). Relative density, ionic conductivity and TLP content must be balanced, because at small d50, although relative density is enhanced the ionic conductivity is reduced. A packing model has been used to understand this behaviour and the mass transfer mechanisms. [-]
Datos relacionados
https://ars.els-cdn.com/content/image/1-s2.0-S0955221924001602-mmc1.docxEntidad financiadora
Generalitat Valenciana | Ministerio de Ciencia, Innovación y Universidades | Universitat Jaume I
Código del proyecto o subvención
MFA/2022/030 | MCIN/AEI/10.13039/501100011033 | POSDOC/2020/04 | ACIF/2021/294 | ACIF/2021/050
Derechos de acceso
0955-2219/© 2024 The Author(s).
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
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