Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols
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Otros documentos de la autoría: Sorribes, Iván; Lemos, Samantha; Martín Solans, Santiago; Mayoral, Álvaro; Lima, Renata C; Andres, Juan
Metadatos
Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7013
comunitat-uji-handle3:10234/8638
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INVESTIGACIONMetadatos
Título
Palladium doping of In2O3 towards a general and selective catalytic hydrogenation of amides to amines and alcoholsAutoría
Fecha de publicación
2019-11Editor
Royal Society of ChemistryISSN
2044-4753; 2044-4761Cita bibliográfica
SORRIBES, Iván, et al. Palladium doping of In 2 O 3 towards a general and selective catalytic hydrogenation of amides to amines and alcohols. Catalysis Science & Technology, 2019, vol. 9, no 24, p. 6965-6976.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://pubs.rsc.org/--/content/articlehtml/2019/cy/c9cy02128kVersión
info:eu-repo/semantics/acceptedVersionPalabras clave / Materias
Resumen
Herein, the first general heterogeneous catalytic protocol for the hydrogenation of primary, secondary and tertiary amides to their corresponding amines and alcohols is described. Advantageously, this catalytic protocol ... [+]
Herein, the first general heterogeneous catalytic protocol for the hydrogenation of primary, secondary and tertiary amides to their corresponding amines and alcohols is described. Advantageously, this catalytic protocol works under additive-free conditions and is compatible with the presence of aromatic rings, which are fully retained in the final products. This hydrogenative C–N bond cleavage methodology is catalyzed by a Pd-doped In2O3 catalyst prepared by a microwave hydrothermal-assisted method followed by calcination. This catalyst displays highly dispersed Pd2+ ionic species in the oxide matrix of In2O3 that have appeared to be essential for its high catalytic performance. [-]
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Catalysis Science & Technology, 2019, vol. 9, no 24Proyecto de investigación
Spanish Ministerio de Ciencia, Innovacion y Universidades: PGC2018-094417-B-I00; Universitat Jaume I: UJI-B2016-25; Spanish Ministerio de Economia, Industria y Competitividad: IJCI-2016-30590; CAPES: 88881.187798/2018-01; CAPES; National Council for Scientific and Technological Development (CNPq); Minas Gerais State Research Foundation (FAPEMIG); Grupo de Materiais Inorganicos do Triangulo (GMIT) - Research Group - FAPEMIG: APQ-00330-14; DGA/fondos FEDER (construyendo Europa desde Aragon): E31_17R SPST of ShanghaiTech University: EM02161943; National Natural Science Foundation of China: NFSC-21850410448, NSFC-21835002Derechos de acceso
© The Royal Society of Chemistry
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