(Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes
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Other documents of the author: Pinto, Mara; Olivares, Marta; Vivancos Ureña, Ángela; Guisado-Barrios, Gregorio; albrecht, martin; Royo, Beatriz
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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https://doi.org/10.1039/C9CY00685K |
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Title
(Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydesAuthor (s)
Date
2019Publisher
Royal Society of ChemistryISSN
2044-4753; 2044-4761Bibliographic citation
PINTO, Mara F., et al. (Di) triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes. Catalysis Science & Technology, 2019, vol. 9, no 10, p. 2421-2425Type
info:eu-repo/semantics/articlePublisher version
https://pubs.rsc.org/en/content/articlehtml/2019/cy/c9cy00685kVersion
info:eu-repo/semantics/publishedVersionSubject
Abstract
Carbonyl manganese complexes with chelating or bridging mesoionic di(1,2,3-triazolylidene) ligands were efficiently synthesised and fully characterised, including the X-ray diffraction study of a bimetallic manganese(0) ... [+]
Carbonyl manganese complexes with chelating or bridging mesoionic di(1,2,3-triazolylidene) ligands were efficiently synthesised and fully characterised, including the X-ray diffraction study of a bimetallic manganese(0) complex. This unprecedented bimetallic complex displayed high yield and selectivity in the catalytic oxidation of secondary alcohols and benzyl alcohol with tert-butyl hydroperoxide under mild conditions. [-]
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Catalysis Science & Technology, 2019, vol. 9, no 10Investigation project
FCT, CERMAX: PTDC/QUI-QIN/28151/2017, PD/BD/105994/2014; European Research Council (ERC): CoG 615653; Swiss National Science Foundation (SNSF): 200021-162868; Spanish Ministry of Economy & Competitiveness: IJCI-2015-2340Rights
© The Royal Society of Chemistry
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