Supported Ionic Liquid‐Like Phases (SILLPs) as Immobilised Catalysts for the Multistep and Multicatalytic Continuous Flow Synthesis of Chiral Cyanohydrins
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Otros documentos de la autoría: Peris, Edgar; Porcar Garcia, Raul; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V.
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https://doi.org/10.1002/cctc.201900086 |
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Título
Supported Ionic Liquid‐Like Phases (SILLPs) as Immobilised Catalysts for the Multistep and Multicatalytic Continuous Flow Synthesis of Chiral CyanohydrinsAutoría
Fecha de publicación
2019ISBN
1867-3880ISSN
1867-3899Cita bibliográfica
PERIS, Edgar, et al. Supported Ionic Liquid‐Like Phases (SILLPs) as Immobilised Catalysts for the Multistep and Multicatalytic Continuous Flow Synthesis of Chiral Cyanohydrins. ChemCatChem, 2019, vol. 11, no 7, p. 1955-1962Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://onlinelibrary.wiley.com/doi/full/10.1002/cctc.201900086Versión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
Supported Ionic Liquid‐Like Phases have been found to be efficient organocatalysts for the synthesis of cyanohydrin esters under solvent‐free conditions by an “electrophile‐nucleophile dual activation” based on hydrogen ... [+]
Supported Ionic Liquid‐Like Phases have been found to be efficient organocatalysts for the synthesis of cyanohydrin esters under solvent‐free conditions by an “electrophile‐nucleophile dual activation” based on hydrogen bond formation. The combination of multiple and consecutive multicatalytic steps in a single and integrated cascade process of organocatalytic SILLPs with commercially available supported Candida antarctica lipase type B (CAL‐B) has allowed developing an efficient process for the multicatalytic synthesis of enantiopure cyanohydrins under flow conditions. [-]
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ChemCatChem, 2019, vol. 11, no 7Proyecto de investigación
G. V.: PROMETEO 2016‐071; MINECO: CTQ2015‐68429R; MICINN: FPU13/00685Derechos de acceso
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