Nanolayered cobalt–molybdenum sulphides (Co–Mo–S) catalyse borrowing hydrogen C–S bond formation reactions of thiols or H2S with alcohols
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Título
Nanolayered cobalt–molybdenum sulphides (Co–Mo–S) catalyse borrowing hydrogen C–S bond formation reactions of thiols or H2S with alcoholsFecha de publicación
2019Editor
Royal Society of ChemistryISSN
2041-6520; 2041-6539Cita bibliográfica
SORRIBES, Iván; CORMA, Avelino. Nanolayered cobalt–molybdenum sulphides (Co–Mo–S) catalyse borrowing hydrogen C–S bond formation reactions of thiols or H2S with alcohols. Chemical Science, 2019, vol. 10, no 10, p. 3130-3142Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
https://pubs.rsc.org/en/content/articlehtml/2019/sc/c8sc05782fVersión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
Nanolayered cobalt–molybdenum sulphide (Co–Mo–S) materials have been established as excellent catalysts for C–S bond construction. These catalysts allow for the preparation of a broad range of thioethers in good to ... [+]
Nanolayered cobalt–molybdenum sulphide (Co–Mo–S) materials have been established as excellent catalysts for C–S bond construction. These catalysts allow for the preparation of a broad range of thioethers in good to excellent yields from structurally diverse thiols and readily available primary as well as secondary alcohols. Chemoselectivity in the presence of sensitive groups such as double bonds, nitriles, carboxylic esters and halogens has been demonstrated. It is also shown that the reaction takes place through a hydrogen-autotransfer (borrowing hydrogen) mechanism that involves Co–Mo–S-mediated dehydrogenation and hydrogenation reactions. A novel catalytic protocol based on the thioetherification of alcohols with hydrogen sulphide (H2S) to furnish symmetrical thioethers has also been developed using these earth-abundant metal-based sulphide catalysts. [-]
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Chemical Science, 2019, vol. 10, no 10Proyecto de investigación
Spanish Government-MINECO through the program "Severo Ochoa": SEV-2016-0683; Vice-Rectorate for Research, Innovation and Transfer of the Universitat Politecnica de Valencia (UPV); Spanish Government-MINECODerechos de acceso
info:eu-repo/semantics/openAccess
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