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dc.contributor.authorRivera-Austrui, J.
dc.contributor.authorMartínez, K.
dc.contributor.authorÁbalos, Manuela
dc.contributor.authorSales Martínez, Carlos
dc.contributor.authorPortolés Nicolau, Tania
dc.contributor.authorBeltrán Arandes, Joaquim
dc.contributor.authorSauló, Jordi
dc.contributor.authorAristizábal, B.H.
dc.contributor.authorAbad, Esteban
dc.date.accessioned2017-11-16T12:29:39Z
dc.date.available2017-11-16T12:29:39Z
dc.date.issued2017-09
dc.identifier.citationRIVERA-AUSTRUI, J., et al. Analysis of polychlorinated dibenzo-p-dioxins and dibenzofurans in stack gas emissions by gas chromatography-atmospheric pressure chemical ionization-triple-quadrupole mass spectrometry. Journal of Chromatography A, 2017, vol. 1513, p. 245-249.ca_CA
dc.identifier.urihttp://hdl.handle.net/10234/170138
dc.description.abstractA gas chromatography coupled to triple-quadrupole mass spectrometry (GC-(QqQ)MS/MS) including a soft-ionization through an atmospheric pressure chemical ionization (APCI) source based method was compared with the high resolution mass spectrometry (HRMS) standard reference method EN1948, for the analysis of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) in stack gas emissions. The stack emission samples were collected, both, by manual method sampling (from 6 to 8 h) and by long-term sampling systems (sampling time of several weeks). This work presents the first comparison of GC-(QqQ)MS/MS with APCI source with the European Standard EN1948 technique for stack gas emissions. Sample concentrations ranged from 0.5 to 596 pg I-TEQ/Nm3. Comparative results in all investigated samples showed relative errors that were within ±15%. These results make GC-(QqQ)MS/MS with APCI suitable for the quantitative analysis of dioxins in the studied samples and create a real alternative tool to the reference sector GC-HRMS instruments.ca_CA
dc.format.extent5 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherElsevierca_CA
dc.rights© 2017 Elsevier B.V. All rights reserved.ca_CA
dc.subjectDioxin analysisca_CA
dc.subjectStack gas emissionsca_CA
dc.subjectEN-1948ca_CA
dc.subjectAPGCca_CA
dc.subjectQqQca_CA
dc.titleAnalysis of polychlorinated dibenzo-p-dioxins and dibenzofurans in stack gas emissions by gas chromatography-atmospheric pressure chemical ionization-triple-quadrupole mass spectrometryca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttps://doi.org/10.1016/j.chroma.2017.07.039
dc.relation.projectIDMinisterio de Economía y Competitividad, Spain (Project: CTQ2011-23618) and Generalitat Valenciana (Project: Collaborative Research on Environment and Food Safety, ISIC/2012/016; Research Group of Excellence PROMETEO/2009/054)ca_CA
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessca_CA
dc.relation.publisherVersionhttp://www.sciencedirect.com/science/article/pii/S002196731731021Xca_CA
dc.contributor.funderUniversidad Nacional de Colombia Sede Manizales ( IDAEA-CSIC)ca_CA
dc.type.versioninfo:eu-repo/semantics/draftca_CA


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