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Analysis of polychlorinated dibenzo-p-dioxins and dibenzofurans in stack gas emissions by gas chromatography-atmospheric pressure chemical ionization-triple-quadrupole mass spectrometry
dc.contributor.author | Rivera-Austrui, J. | |
dc.contributor.author | Martínez, K. | |
dc.contributor.author | Ábalos, Manuela | |
dc.contributor.author | Sales Martínez, Carlos | |
dc.contributor.author | Portoles, Tania | |
dc.contributor.author | Beltran Arandes, Joaquin | |
dc.contributor.author | Sauló, Jordi | |
dc.contributor.author | Aristizábal, B.H. | |
dc.contributor.author | Abad, Esteban | |
dc.date.accessioned | 2017-11-16T12:29:39Z | |
dc.date.available | 2017-11-16T12:29:39Z | |
dc.date.issued | 2017-09 | |
dc.identifier.citation | RIVERA-AUSTRUI, J., et al. Analysis of polychlorinated dibenzo-p-dioxins and dibenzofurans in stack gas emissions by gas chromatography-atmospheric pressure chemical ionization-triple-quadrupole mass spectrometry. Journal of Chromatography A, 2017, vol. 1513, p. 245-249. | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/170138 | |
dc.description.abstract | A gas chromatography coupled to triple-quadrupole mass spectrometry (GC-(QqQ)MS/MS) including a soft-ionization through an atmospheric pressure chemical ionization (APCI) source based method was compared with the high resolution mass spectrometry (HRMS) standard reference method EN1948, for the analysis of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) in stack gas emissions. The stack emission samples were collected, both, by manual method sampling (from 6 to 8 h) and by long-term sampling systems (sampling time of several weeks). This work presents the first comparison of GC-(QqQ)MS/MS with APCI source with the European Standard EN1948 technique for stack gas emissions. Sample concentrations ranged from 0.5 to 596 pg I-TEQ/Nm3. Comparative results in all investigated samples showed relative errors that were within ±15%. These results make GC-(QqQ)MS/MS with APCI suitable for the quantitative analysis of dioxins in the studied samples and create a real alternative tool to the reference sector GC-HRMS instruments. | ca_CA |
dc.format.extent | 5 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Elsevier | ca_CA |
dc.rights | © 2017 Elsevier B.V. All rights reserved. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Dioxin analysis | ca_CA |
dc.subject | Stack gas emissions | ca_CA |
dc.subject | EN-1948 | ca_CA |
dc.subject | APGC | ca_CA |
dc.subject | QqQ | ca_CA |
dc.title | Analysis of polychlorinated dibenzo-p-dioxins and dibenzofurans in stack gas emissions by gas chromatography-atmospheric pressure chemical ionization-triple-quadrupole mass spectrometry | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1016/j.chroma.2017.07.039 | |
dc.relation.projectID | Ministerio de Economía y Competitividad, Spain (Project: CTQ2011-23618) and Generalitat Valenciana (Project: Collaborative Research on Environment and Food Safety, ISIC/2012/016; Research Group of Excellence PROMETEO/2009/054) | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | http://www.sciencedirect.com/science/article/pii/S002196731731021X | ca_CA |
dc.contributor.funder | Universidad Nacional de Colombia Sede Manizales ( IDAEA-CSIC) | ca_CA |
dc.type.version | info:eu-repo/semantics/draft | ca_CA |
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