Comprehensive strategy for pesticide residue analysis through the production cycle of gilthead sea bream and Atlantic salmon
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Scholar |
Otros documentos de la autoría: Portoles, Tania; Ibáñez, Maria; Garlito Molina, Borja; Nácher Mestre, Jaime; Karalazos, Vasileios; Silva, Joana; Alm, Martin; Serrano, Roque; Pérez Sánchez, Jaume; Hernandez, Felix; Berntssen, Marc H. G.
Metadatos
Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/33596
comunitat-uji-handle3:10234/33597
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INVESTIGACIONMetadatos
Título
Comprehensive strategy for pesticide residue analysis through the production cycle of gilthead sea bream and Atlantic salmonAutoría
Fecha de publicación
2017-07Editor
ElsevierISSN
0045-6535; 1879-1298Cita bibliográfica
PORTOLÉS, T., et al. Comprehensive strategy for pesticide residue analysis through the production cycle of gilthead sea bream and Atlantic salmon. Chemosphere, 2017, vol. 179, p. 242-253.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://www.sciencedirect.com/science/article/pii/S004565351730471XVersión
info:eu-repo/semantics/submittedVersionPalabras clave / Materias
Resumen
Plant ingredients and processed animal proteins are alternative feedstuffs for fish feeds in aquaculture. However, their use can introduce contaminants like pesticides that are not previously associated with marine ... [+]
Plant ingredients and processed animal proteins are alternative feedstuffs for fish feeds in aquaculture. However, their use can introduce contaminants like pesticides that are not previously associated with marine Atlantic salmon and gilthead sea bream farming. This study covers the screening of around 800 pesticides by gas chromatography (GC) and liquid chromatography (LC) coupled to high resolution time-of-flight mass spectrometry in matrices throughout the entire marine food production chain. Prior to analysis of real-world samples, the screening methodology was validated for 252 pesticides to establish the screening detection limit. This was 0.01 mg kg−1 for 113 pesticides (45%), 0.05 mg kg−1 for 73 pesticides (29%) and >0.05 mg kg−1 for 66 pesticides (26%). After that, a quantitative methodology based on GC coupled to tandem mass spectrometry with atmospheric pressure chemical ionization source (GC-APCI-MS/MS) was optimized for the pesticides found in the screening. Although several polar pesticides, of which pirimiphos methyl and chlorpyriphos-methyl were most dominant, were found in plant material and feeds based on these ingredients, none of them were observed in fillets of Atlantic salmon and gilthead sea bream fed on these feeds. [-]
Publicado en
Chemosphere, 2017, vol. 179Derechos de acceso
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