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Secondary Amine Catalysis in Enzyme Design: Broadening Protein Template Diversity through Genetic Code Expansion
Wiley (2024)Secondary amines, due to their reactivity, can transform protein templates into catalytically active entities, accelerating the development of artificial enzymes. However, existing methods, predominantly reliant on modified ... -
Selective conversion of various monosaccharaides into sugar acids by additive‐free dehydrogenation in water
Wiley (2020)Abundant sugars of five and six carbon atoms are promising candidates for the production of valuable platform chemicals. Here, we describe the catalytic dehydrogenation of several pentoses and hexoses into their corresponding ... -
Selective Growth of Layered Perovskites for Stable and Efficient Photovoltaics
Royal Society of Chemistry (2018-11)Perovskite solar cells (PSCs) are promising alternatives toward clean energy because of their high-power conversion efficiency (PCE) and low materials and processing cost. However, their poor stability under operation ... -
Self-Assembly of Di-N-Heterocyclic Carbene-Gold-Adorned Corannulenes on C60
Wiley (2017-08-04)The deprotonation of a corannulene-based bisazolium salt allowed the preparation of a corannulene-based NHC di-AuI complex. The prepared di-AuI-complex was tested in the recognition of fullerene-C60, demonstrating good ... -
Self-supported ultra-active NiO-based electrocatalysts for the oxygen evolution reaction by solution combustion
Royal Society of Chemistry (2021-04-20)The oxygen evolution reaction (OER) is a fundamental process to develop a technology that can drive energy transition towards renewable and sustainable fuels. Nevertheless, efficient and straightforward methodologies to ... -
Semiconductor α‐Fe2O3 Hematite Fabricated Electrode for Sensitive Detection of Phenolic Pollutants
Wiley (2018-11-23)Hematite (α‐Fe2O3) semiconductor is an abundant and non‐toxic catalyst for different (photo)electrochemical reactions. In this work, a selective p‐nitrophenol sensor was developed by fabricating a thin‐layer of a glassy ... -
Separating bulk and surface processes in NiOx electrocatalysts for water oxidation
Royal Society of Chemistry (2020-08-10)Nickel oxide-based catalysts currently represent the state of the art in electrochemical water oxidation in alkaline pH. However, much of their functionality remains poorly understood, particularly regarding catalytically ... -
Shape-Adaptability and Redox-Switching Properties of a Di-Gold Metallotweezer
Wiley (2021-04-12)The use of a carbazolyl-connected di-gold(I) metallotweezer for the encapsulation of several electron-poor organic substrates, and a planar Au(III) complex containing a CNC pincer ligand, is described. The binding affinity ... -
Simultaneous Color Restoration and Depth Estimation in Light Field Imaging
(2022-05-03)Recent studies in the light field imaging have shown the potential and advantages of different light field information processes. In most of the existing techniques, the processing pipeline of light field has been treated ... -
Single Step Deposition of an Interacting Layer of Perovskite Matrix with Embedded Quantum Dots
Royal Society of Chemistry (2016)Hybrid lead halide perovskite (PS) derivatives have emerged as very promising materials for the development of optoelectronic devices in the last few years. At the same time, inorganic nanocrystals with quantum confinement ... -
Single-Exciton Amplified Spontaneous Emission in Thin Films of CsPbX3 (X = Br, I) Perovskite Nanocrystals
American Chemical Society (2019-09-23)CsPbX3 perovskite nanocrystals (PNCs) have emerged as an excellent material for stimulated emission purposes, with even more prospective applications than conventional colloidal quantum dots. However, a better understanding ... -
Single-Walled Carbon Nanotubes Encapsulated within Metallacycles
Wiley (2022-09-26)Mechanically interlocked derivatives of carbon nanotubes (MINTs) are interesting nanotube products since they show high stability without altering the carbon nanotube structure. So far, MINTs have been synthesized using ... -
Smart N-Heterocyclic Carbene Ligands in Catalysis
American Chemical Society (2017)It is well-recognized that N-heterocyclic carbene (NHC) ligands have provided a new dimension to the design of homogeneous catalysts. Part of the success of this type of ligands resides in the limitless access to a variety ... -
Solar Energy Storage by a Heterostructured BiVO4–PbOx Photocapacitive Device
American Chemical Society (2017)The development of solar energy storage strategies is a key step for handling the inherent variability of sunlight within a global solar-based energy model. In the present study, we have developed a photocapacitive device ... -
Solution-Processed Ni-Based Nanocomposite Electrocatalysts: An Approach to Highly Efficient Electrochemical Water Splitting
American Chemical Society (2021-05-10)In this study, we report an up-scalable and low-cost solution-processed method to in situ synthesize an earth-abundant non-stoichiometric NiOx-based electrocatalytic film for water oxidation. The catalytic activity was ... -
Solvent-Mediated Structural Evolution Mechanism from Cs4PbBr6 to CsPbBr3 Crystals
MDPI (2021-07-05)The study of the solvent-mediated structural evolution mechanism of the Cs4PbBr6 powders prepared using the solvothermal method is presented. The Cs4PbBr6 powders with a rhombohedral structure and an intense green emission ... -
Spectral properties of the dynamic state transition in metal halide perovskite-based memristor exhibiting negative capacitance
American Institute of Physics (2021-02-15)The evolution of device properties in memristor switching between high- and low-resistance states is critical for applications and is still highly subjected to significant ambiguity. Here, we present the dynamic state ... -
Spectroelectrochemical Analysis of the Water Oxidation Mechanism on Doped Nickel Oxides
American Chemical Society (2022-04-20)Metal oxides and oxyhydroxides exhibit state-of-the-art activity for the oxygen evolution reaction (OER); however, their reaction mechanism, particularly the relationship between charging of the oxide and OER kinetics, ... -
Spin Coherence and Relaxation Dynamics of Localized Electrons and Holes in FAPbI3 Films
ACS Publications (2024-07-04)We obtained highly stable polycrystalline thin films of FAPbI3 prepared under air ambient conditions. In these materials, the presence of Pb–O bonds prevents the propagation of α- to δ-FAPbI3 phase conversion and allowed ...