Listar INAM_Articles por título
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A Comparative Study of Light‐Emitting Diodes Based on All‐Inorganic Perovskite Nanoparticles (CsPbBr3) Synthesized at Room Temperature and by a Hot‐Injection Method
Wiley-VCH Verlag (2018-04)Perovskite nanoparticles (PeNPs) have been extensively studied for optoelectronic applications, owing to their extremely high photoluminescence quantum yield, tunable band gap, and exceptionally narrow emission spectra. ... -
A D3h-symmetry hexaazatriphenylene-tris-N-heterocyclic carbene ligand and its coordination to iridium and gold: preliminary catalytic studies
Royal Society of Chemistry (2017)A new D3h-symmetry tris-N-heterocyclic carbene ligand has been prepared and coordinated to iridium and gold. The ligand contains an electron-poor hexaazatriphenylene core; thus, the resulting tris-NHC ligand is a poor ... -
A Deeper Insight into the Supramolecular Activation of Oxidative Addition Reactions Involving Pincer-Rhodium (I) Complexes
Wiley (2024-01-25)The factors governing the acceleration of the oxidative addition of methyl iodide to pincer rhodium(I)-complexes induced by coronene have been computationally explored in detail using quantum chemical methods. Both the ... -
A Dinuclear Au(I) Complex with a Pyrene-di-N-heterocyclic Carbene Linker: Supramolecular and Catalytic Studies
American Chemical Society (2018)A digold(I) complex with a pyrene-di-N-heterocyclic carbene ligand has been obtained and fully characterized. The host–guest properties of the complex were studied in chloroform with a series of polycylic aromatic hydrocarbons ... -
A discussion on the possible involvement of singlet oxygen in oxygen electrocatalysis
IOP Publishing (2021-05-11)The dioxygen molecule has two bound states, singlet and triplet, which are different in energy, lifetime, and reactivity. In the context of oxygen electrocatalysis as applied to fuel cells and water splitting the involved ... -
A first-principles study of the stability, electronic structure, and optical properties of halide double perovskite Rb2Sn1xTexI6 for solar cell applications
Royal Society of Chemistry (2021-01-22)Owing to their emerging role in solar cell technology, lead halide perovskites have aroused significant research interest in the recent past. However, due to its obvious toxicity, looking for a potential alternative to ... -
A Frequency Domain Analysis of the Excitability and Bifurcations of the FitzHugh–Nagumo Neuron Model
American Chemical Society (2021-11-18)The dynamics of neurons consist of oscillating patterns of a membrane potential that underpin the operation of biological intelligence. The FitzHugh−Nagumo (FHN) model for neuron excitability generates rich dynamical ... -
A low temperature aqueous formate fuel cell using cobalt hexacyanoferrate as a non-noble metal oxidation catalyst
Royal Society of Chemistry (2020-12-01)Cobalt hexacyanoferrate, the Co–Fe Prussian blue derivative (CoFePB), is an effective, selective and stable electrocatalyst for formate oxidation, exhibiting robust performance under a variety of electrolyte conditions. ... -
A Matter of Fidelity: Self‐Sorting Behavior of Di‐Gold Metallotweezers
Wiley (2019-06)Cation‐induced high selective self‐sorting is observed for reactions involving a series of di‐gold metallotweezers. The variation of the nature of the arms of the tweezers (benzo‐imidazolylidene or pyrene‐imidazolylidene), ... -
A metal-organic framework converted catalyst that boosts photo-electrochemical water splitting
Royal Society of Chemistry (2019-04-08)Realization of photo-electrochemical water splitting to generate H2 alternative fuel requires the facilitation of the kinetically-sluggish oxygen evolution reaction (OER) occurring at the photoanode. To do so, there is a ... -
A palladium-hinged organometallic square with a perfect-sized cavity for the encapsulation of three heteroguests
Royal Society of Chemistry (2019-12-25)A nanometer-sized tetrapalladium metallosquare with a pyrene-bisimidazolylidene ligand was found to display a perfect-sized cavity for the encapsulation of three heteroguests, enabling the formation of quintuple D–A–D–A–D ... -
A Perovskite Photovoltaic Mini-Module-CsPbBr3 Photoelectrochemical Cell Tandem Device for Solar-Driven Degradation of Organic Compounds
American Chemical Society (2023-10-02)Recently, halide perovskites have been widely explored for high-efficiency photocatalysis or photoelectrochemical (PEC) cells. Here, in order to make an efficient photoanode electrode for the degradation of pollutants, ... -
A Perspective on the Commercial Viability of Perovskite Solar Cells
Wiley (2021-11-04)Perovskite solar cells (PSCs) have received a large amount of research funds due to their potential as a frontrunner in a new generation of solar cells; consequently, the desire to commercialize this technology is mounting. ... -
A Platinum molecular complex immobilised on the surface of graphene as active catalyst in alkyne hydrosilylation
Wiley (2020-05-11)Abstract A platinum complex bearing a N‐heterocyclic carbene (NHC) ligand functionalised with a pyrene‐tag is immobilised onto the surface of reduced graphene oxide (rGO). The hybrid material composed of an organometallic ... -
A QM/MM study on the origin of retro-aldolase activity of a catalytic antibody
The Royal Society of Chemistry (2021-04-26)The retro-aldolase mechanism of methodol catalysed by the catalytic antibody 33F12 is described based on the exploration of the free energy landscape obtained with QM/MM methods. The amino acids involved in the reaction ... -
A Rational Approach to Improve the Overall Performances of Semitransparent Perovskite Solar Cells by Electrode Optical Management
American Chemical Society (2024)Improving the overall characteristics of semitransparent solar cells (STSCs) is a very hard goal, not only because the absorption and the transmission of light through the device are two competitive processes but also ... -
A redox-switchable catalyst with an 'unplugged' redox tag
Royal Society of Chemistry (2022-08-24)Two bis-(propyl-imidazolium)-napthalenediimide (NDI) salts were prepared and used as N-heterocyclic carbene (NHC) precursors for the preparation of dimetallic complexes of rhodium and iridium. Infrared spectroelectrochemical ... -
A Redox-Switchable Gold(I) Complex for the Hydroamination of Acetylenes: A Convenient Way for Studying Ligand-Derived Electronic Effects
American Chemical Society (2022-03-31)A gold complex with a naphthalene-di-imide-functionalized N-heterocyclic carbene (NHC) ligand was prepared and characterized. The electrochemical studies reveal that the complex is able to undergo two successive reduction ... -
A resorcinarene-based tetrabenzoimidazolylidene complex of rhodium
Royal Society of Chemistry (2020-03-14)A tetrabenzoimidazolium-resorcinarene cavitand was used for the preparation of a tetra-benzoimidazolylidene of rhodium, which is unprecedented in the field of poly-NHC metal complexes. Both, the experimental and computational ... -
A Rigid Trigonal‐Prismatic Hexagold Metallocage That Behaves as a Coronene Trap
Wiley (2019-05-13)A trigonal‐prismatic hexagold cage was obtained by combining a triphenylene‐tris(N‐heterocyclic carbene) ligand and a carbazolyl‐bis(alkynyl) linker. The metallocage has a slot‐like cavity with a volume of about 300 Å3. ...