ListarInstitute of Advanced Materials (INAM) por tema "N-heterocyclic carbene"
Mostrando ítems 1-8 de 8
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A Redox-Switchable Gold(I) Complex for the Hydroamination of Acetylenes: A Convenient Way for Studying Ligand-Derived Electronic Effects
American Chemical Society (2022-03-31)A gold complex with a naphthalene-di-imide-functionalized N-heterocyclic carbene (NHC) ligand was prepared and characterized. The electrochemical studies reveal that the complex is able to undergo two successive reduction ... -
A Shape‐Adaptable Organometallic Supramolecular Coordination Cage for the Encapsulation of Fullerenes
Wiley (2018-10-01)The development of three‐dimensional supramolecular coordination complexes (SCCs), with cavities suitable for guest binding, is of great interest because these materials are useful in a large number of applications. Herein, ... -
Gold(I) Complex with a Photoactive Ligand Behaves as a Two-in-One Dual Metallaphotoredox Cross-Coupling Catalyst
American Chemical Society (2024-02-29)We herein describe the use of a gold complex with a naphthalene-di-imide-functionalized N-heterocyclic carbene (NDI-NHC) ligand, which was used as a photocatalyst for a variety of reactions. Due to the presence of the ... -
Gold(I) Metallo‐Tweezers for the Recognition of Functionalized Polycyclic Aromatic Hydrocarbons by Combined π–π Stacking and H‐Bonding
Wiley (2017)Two gold(I)‐based metallo‐tweezers with bis(Au−NHC) pincers and a carbazole connector have been obtained and used for the recognition of polycyclic aromatic hydrocarbons (PAHs). In the case of the tweezer with pyrene–NHC ... -
Lone-Pair-π Bond Strength Unveiled by a Combined Experimental and Computational Study
Wiley (2024-08-05)A series of naphthalene-diimide (NDI) and perylene-diimide (PDI) connected bis-N-heterocyclic carbene complexes of iridium(III) have been prepared and fully characterized. The analysis of their NMR spectroscopic features, ... -
Redox-Switchable Complexes Based on Nanographene-NHCs
Wiley (2022-05-30)A series of rhodium and iridium complexes with a N-heterocyclic carbene (NHC) ligand decorated with a perylene-diimide-pyrene moiety are described. Electrochemical studies reveal that the complexes can undergo two successive ... -
Self-Assembly of Di-N-Heterocyclic Carbene-Gold-Adorned Corannulenes on C60
Wiley (2017-08-04)The deprotonation of a corannulene-based bisazolium salt allowed the preparation of a corannulene-based NHC di-AuI complex. The prepared di-AuI-complex was tested in the recognition of fullerene-C60, demonstrating good ... -
Template‐Controlled Synthesis of Polyimidazolium Salts by Multiple [2+2] Cycloaddition Reactions
Wiley (2020-09-04)The tetrakisimidazolium salt H4‐2(Br)4, featuring a central benzene linker and 1,2,4,5‐(nBu‐imidazolium‐Ph‐CH=CH‐) substituents reacts with Ag2O in the presence of AgBF4 to yield the tetranuclear, oktakis‐NHC assembly ...