Listar por tema "Carbens"
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Double CH bond activation of C(sp3)H2 groups for the preparation of complexes with back-to-back bisimidazolinylidenes
Wiley (2011-06-29)Two-headed carbenes: N-heterocyclic carbene complexes of rhodium and iridium were obtained by the double CH activation of CH2 groups in N heterocycles (see structure: C gray, N blue, Cl green, Ir pink). The reaction ... -
Water-soluble IrIII n-heterocyclic carbene based catalysts for the reduction of CO2 to formate by transfer hydrogenation and the deuteration of aryl amines in water
WILEY-VCH Verlag (2011-03-01)Two new water-soluble [IrI2(AcO)(bis-NHC)] complexes (NHC=N-heterocyclic carbene) incorporating a sulfonate functionality have been synthesized. The two complexes have been tested in the reduction of CO2 with H2 and iPrOH, ...