Listar por autoría "7cdbfb22-4ae5-4540-a080-fab600da8ad6"
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An Unusual Example of Base-Free Catalyzed Reduction of C═O and C═NR Bonds by Transfer Hydrogenation and Some Useful Implications
Corberán Roc, Rosa; Peris, Eduardo American Chemical Society (2008-03)A series of Cp*IrIII(NHC) complexes have been used in the catalytic transfer hydrogenation of ketones and imines in iPrOH, showing that the reduction of ketones is complete within minutes at room temperature, with the ... -
Cp*Ir(NHC) complexes as highly versatile and efficient catalysts for the cross-coupling of alcohols and amines
Prades Ferrer, Amparo; Corberán Roc, Rosa; Poyatos, Macarena; Peris, Eduardo Wiley-VCH (2008-11-19)A comparative study on the catalytic activity of a series of Cp*Ir(NHC)Cl2 complexes in several C-O and C-N coupling processes implying hydrogen-borrowing mechanisms has been performed. The compound Cp*Ir(InBu)Cl2 (InBu ... -
First Cyclic Carbodiphosphoranes of Copper(I) and Gold(I) and Their Application in the Catalytic Cleavage of X−H Bonds (X = N and O)
Corberán Roc, Rosa; Marrot, Sebastien; Dellus, Nicolas; Merceron-Saffon, Nathalie; Kato, Tsuyoshi; Peris, Eduardo; Baceiredo, Antoine American Chemical Society (2009)Three new carbodiphosphorane complexes, (PHCP)M(tBuO) (PHCP = carbodiphosphorane; M = Cu, Au) and (PHCP)CuCl, were readily prepared by reaction of the carbodiphosphorane 2 with CuCl or AuCl(Me2S). The three complexes have ...