Listar por autoría "5e2ec60e-88d7-4ae0-b3c3-757275a391e4"
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Perceptible Influence of Pd and Pt Heterocyclic Carbene–Pyridyl Complexes in Catalytic Diboration of Cyclic Alkenes
Pubill Ulldemolins, Cristina; Bo, Carles; Mata Martínez, Jose A; Fernández, Elena Wiley-VCH (2010)Bis(catecholato)diboron was added to cyclic alkenes with internal strain to selectively form bis(boryl)cycloalkanes quantitatively in the presence of [Pd(NHC)pyCl2], [Pd(NHC)pyI2], and [Pt(NHC)pyI2] (NHC=N-heterocyclic ... -
Rhodium–NHC complexes mediate diboration versus dehydrogenative borylation of cyclic olefins: a theoretical explanation†
Pubill Ulldemolins, Cristina; Poyatos, Macarena; Bo, Carles; Fernández, Elena Royal Society of Chemistry (2013)In rhodium catalysed borylation of cyclic olefins, the synergy between bidentate NHC ligands, that modify cationic Rh(I) species, and the use of non-polar solvents, such as cyclohexane, is the key factor to favour a less ...