Listar por autoría "498f8f39-5b87-42b0-a08c-6fdcc92f3957"
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Chemoenzymatic synthesis of optically active 2-(2- or 4-substituted-1H-imidazol-1-yl)cycloalcanols. Chiral additives for (L)-proline
Porcar Garcia, Raul; Ríos-Lombardía, Nicolás; Busto, Eduardo; Gotor Fernández, Vicente; Gotor Fernández, Vicente; Garcia-Verdugo, Eduardo; Burguete, M. Isabel; Luis, Santiago V. Royal Society of Chemistry (2013-04-03)Enantiopure substituted imidazoles obtained by enzymatic kinetic resolution can be promising candidates as co-catalysts for aldol reactions catalysed by (L)-proline. These additives seem to form supramolecular complexes ... -
Chiral Triazolium Salts and Ionic Liquids: From the Molecular Design Vectors to Their Physical Properties through Specific Supramolecular Interactions
Luis, Santiago V.; Porcar Garcia, Raul; Ríos-Lombardía, Nicolás; Busto, Eduardo; Gotor Fernández, Vicente; Montejo Bernardo, José; Garcia-Granda, Santiago; Luis, Santiago V.; Gotor Fernández, Vicente; Alfonso Rodríguez, Ignacio; Garcia-Verdugo, Eduardo Wiley-VCH (2012-11-29)An exhaustive experimental study based on X-ray diffraction analysis, NMR, FTIR-ATR (attenuated total reflection), and Raman spectroscopy as well as theoretical calculations is reported in order to understand how the ... -
Enantiopure triazolium salts. Chemoenzymatic synthesis and applications in organocatalysis
Luis, Santiago V.; Garcia-Verdugo, Eduardo; Ríos-Lombardía, Nicolás; Porcar Garcia, Raul; Busto, Eduardo; Alfonso Rodríguez, Ignacio; Montejo Bernardo, José; Garcia-Granda, Santiago; Gotor Fernández, Vicente Wiley-VCH Verlag GmbH & Co. KGaA (2011-10-14)A novel family of triazolium salt enantiomers has been efficiently synthesized by combining chemical and biocatalytic methods. The stereoselective action shown by hydrolytic enzymes led to the design of simple and general ... -
From Salts to Ionic Liquids by Systematic Structural Modifications: A Rational Approach Towards the Efficient Modular Synthesis of Enantiopure Imidazolium Salts
Ríos-Lombardía, Nicolás; Busto, Eduardo; Gotor Fernández, Vicente; Porcar Garcia, Raul; Garcia-Verdugo, Eduardo; Luis, Santiago V.; Alfonso Rodríguez, Ignacio; Garcia-Granda, Santiago; Menéndez Velázquez, Amador Wiley-VCH (2010)This paper reports a simple and robust modular synthetic strategy that leads to a large variety of configurationally and structurally diverse imidazole-based chiral ionic liquids (CILs) by lipase-catalyzed resolution. The ... -
Stereoselective chemoenzymatic synthesis of enantiopure 2-(1H-imidazol-yl)cycloalkanols under continuous flow conditions
Burguete, M. Isabel; Luis, Santiago V.; Garcia-Verdugo, Eduardo; Porcar Garcia, Raul; Sans, Victor; Ríos-Lombardía, Nicolás; Gotor Fernández, Vicente; Gotor Fernández, Vicente American Chemical Society (2012-07)The development of continuous flow processes for the synthesis of chiral enantiopure 1-(2-hydroxycycloalkyl)imidazoles is reported. For the ring-opening reaction microwave batch processes and continuous flow reactions have ...