Unveiling the stereoelectronic properties of a triphenylene-based tris N-heterocyclic carbene
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Other documents of the author: Gonell, Sergio; Alabau, Roberto G.; Poyatos, Macarena; Peris, Eduardo
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http://dx.doi.org/10.1039/C3CC44109A |
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Title
Unveiling the stereoelectronic properties of a triphenylene-based tris N-heterocyclic carbeneDate
2013-06-14Publisher
Royal Society of ChemistryISSN
1359-7345; 1364-548XBibliographic citation
GONELL, Sergio, et al. Unveiling the stereoelectronic properties of a triphenylene-based tris N-heterocyclic carbene. Chemical Communications, 2013, vol. 49, no 64, p. 7126-7128Type
info:eu-repo/semantics/articleSubject
Abstract
Two rhodium complexes with a triphenylene-based tris-NHC have been fully characterized. DFT and electrochemical studies suggest that the electronic communication between the metals is very weak, and that the electron ... [+]
Two rhodium complexes with a triphenylene-based tris-NHC have been fully characterized. DFT and electrochemical studies suggest that the electronic communication between the metals is very weak, and that the electron donating properties of the ligand are very similar to those shown by its benzimidazolylidene analogue. [-]
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Chemical Communications, 2013, vol. 49, no 64Rights
© Royal Society of Chemistry 2014
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