Short, Stereoselective Synthesis of the Naturally Occurring Pyrrolidine Radicamine B and a Formal Synthesis of Nectrisine
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Scholar |
Otros documentos de la autoría: Ribés Vidal, Celia; Falomir, Eva; Carda, Miguel; Marco, J. Alberto
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http://dx.doi.org/10.1021/jo8012989 |
Metadatos
Título
Short, Stereoselective Synthesis of the Naturally Occurring Pyrrolidine Radicamine B and a Formal Synthesis of NectrisineFecha de publicación
2008Editor
American Chemical SocietyISSN
0022-3263Cita bibliográfica
Journal of Organic Chemistry, 73, 19, p. 7779–7782Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/abs/10.1021/jo8012989Palabras clave / Materias
Resumen
A short, stereoselective synthesis of the naturally occurring pyrrolidine radicamine B is reported. Garner′s (R)-aldehyde, prepared from d-serine, was the chiral starting material. The pyrrolidine ring was stereosel ... [+]
A short, stereoselective synthesis of the naturally occurring pyrrolidine radicamine B is reported. Garner′s (R)-aldehyde, prepared from d-serine, was the chiral starting material. The pyrrolidine ring was stereoselectively created in a very efficient way through a five-step, one-pot transformation. In addition, an intermediate of this synthesis was transformed into an intermediate of a previously published synthesis of the potent α-glucosidase inhibitor nectrisine. [-]
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