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Towards highly efficient continuous-flow catalytic carbon dioxide cycloadditions with additively manufactured reactors
(The Royal Society of Chemistry, 2022-03-22)
Developing efficient and sustainable methodologies to transform CO2 into added-value chemicals is an important strategy for decarbonization in the chemical industry. Here, a new multi-scale approach for the cycloaddition ...
Tuneable 3D printed bioreactors for transaminations under continuous-flow
(Royal Society of Chemistry, 2017-11-21)
A method to efficiently immobilize enzymes on 3D printed continuous-
fl
ow devices is presented. Application of these chemically
modi
fi
ed devices enables rapid screening of immobilization
mechanisms and ...
Chemo-enzymatic production of omega-3 monoacylglycerides using sponge-like ionic liquids and supercritical carbon dioxide
(Royal Society of Chemistry, 2020-07-22)
A clean chemo-enzymatic synthesis of omega-3 monoacylglycerides was carried out by two consecutive catalytic steps, the enzymatic transesterification of raw fish or linseed oil with solketal for producing fatty acid solketyl ...
Poly(acrylamide-homocysteine thiolactone) as a synthetic platform for the preparation of polymeric ionic liquids by post ring-openingorthogonal modifications
(Royal Society of Chemistry, 2017)
Poly(Acrylamide-Homocysteine Thiolactone) (PAHT) obtained by RAFT polymerisation can be used as a
starting material for the synthesis, through its post modification, of a variety of advanced polymeric
materials with ...
Free ion diffusivity and charge concentration on cross-linked polymeric ionic liquid iongel films based on sulfonated zwitterionic salts and lithium ions
(Royal Society of Chemistry, 2019)
The properties of various mixtures of a zwitterionic ionic liquid (ZIs-1) and LiNTf2, including their conductivity, have been studied showing how they can be adjusted through their molar composition. Conductivity tends to ...
Biocatalytic synthesis of oxygenated biofuels through the technologies of ionic liquids and supercritical carbon dioxide
(Sociedad Española de Biotecnología, 2019-06-10)
The increase in the production of biofuels has generated in the market an excess of glycerol as a byproduct. Some glycerol derivatives, such as solketal (1,2-isopropylidene glycerol), have been used
successfully to ...
Dimethyl carbonate as a non-innocent benign solvent for the multistep continuous flow synthesis of amino alcohols
(Royal Society of Chemistry, 2018)
An efficient methodology for the production and resolution of amino alcohols with a low environmental impact has been developed. The system is based on the assembly of three different well compartmentalised catalytic modules ...
Divergent Multistep Continuous Synthetic Transformations of Allylic Alcohol Enabled by Catalysts Immobilized in Ionic Liquid Phases
(Wiley, 2019-04-23)
Two individual catalytic platforms (metal‐ and organo‐catalyzed) based on the use of an ionic liquid phase were successfully integrated for the synthesis of α‐cyano‐amine and cyanohydrin trimethylsilyl ethers from allylic ...
Hierarchically structured polymeric ionic liquids and polyvinypyrrolidonee mat-fibers fabricated by electrospinning
(Royal Society of Chemistry, 2017-04)
Different polymeric ionic liquids/polyvinylpyrrolidone (PILs/PVP) fiber membranes were prepared by electrospinning from the corresponding polymeric blends. Supramolecular interpolymeric interactions between PILs and PVP ...
Highly Selective Anion Template Effect in the Synthesis of Constrained Pseudopeptidic Macrocyclic Cyclophanes
(American Chemical Society, 2019-12-20)
Herein, we report the synthesis of a novel family of constrained pseudopeptidic macrocyclic compounds containing the hexahydropyrrolo[3,4-f]isoindolocyclophane scaffold and involving four coupled substitution reactions in ...