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Conductivity and Polarization Processes in Highly Cross-Linked Supported Ionic Liquid-Like Phases
(American Chemical Society, 2010)
Supported ionic liquid-like phases were prepared by anchoring imidazolium moieties onto highly cross-linked poly(p-chloromethylstyrene-co-divinylbenzene) monolithic matrixes. The influence of the chemical nature of the ...
Synergy between supported ionic liquid-like phases and immobilized palladium N-heterocyclic carbene–phosphine complexes for the Negishi reaction under flow conditions
(Beilstein-Institut, 2020)
The combination of supported ionic liquids and immobilized NHC–Pd–RuPhos led to active and more stable systems for the Negishi reaction under continuous flow conditions than those solely based on NHC–Pd–RuPhos. The fine ...
Chiral Triazolium Salts and Ionic Liquids: From the Molecular Design Vectors to Their Physical Properties through Specific Supramolecular Interactions
(Wiley-VCH, 2012-11-29)
An exhaustive experimental study based on X-ray diffraction analysis, NMR, FTIR-ATR (attenuated total reflection), and Raman spectroscopy as well as theoretical calculations is reported in order to understand how the ...
Highly selective biocatalytic synthesis of monoacylglycerides in sponge-like ionic liquids
(The Royal Society of Chemistry, 2016-08)
The biocatalytic synthesis of monoacylglycerides (MAGs) was carried out by the direct esterification of fatty acids (i.e. capric, lauric, myristic, palmitic and oleic acids, respectively) with glycerol in different ionic ...
Clean enzymatic preparation of oxygenated biofuels from vegetable and waste cooking oils by using spongelike ionic liquids technology
(American Chemical Society, 2016)
The biocatalytic synthesis of oxygenated biofuels
(fatty acid solketal esters, FASEs) and biodiesel (fatty acid
methyl esters, FAMEs) was carried out by both the direct
esterification of fatty acids (i.e., lauric, ...
A bioinspired approach toward efficient supramolecular catalysts for CO2 conversion
(Elsevier, 2022-12-21)
Nature uses enzymes for affording astonishingly efficient chemical transformations with high chemo-, regio-, and stereoselectivity (e.g., carbonic anhydrase for CO2 conversion). Such sophisticated biomolecules lead to ...
Active biopolymers in green non-conventional media: a sustainable tool for developing clean chemical processes
(Royal Society of Chemistry, 2015-10-15)
The greenness of chemical processes turns around two main axes: the selectivity of catalytic transformations, and the separation of pure products. The transfer of the exquisite catalytic efficiency shown by enzymes in ...
Green bioprocesses in sponge-like ionic liquids
(Elsevier, 2015-10-15)
Ionic liquids (ILs) are a new class of liquid solvent, whose use has led to a green chemical revolution because of their unique array of physico-chemical properties, headed by their negligible vapour pressure and their ...
Microwave-Assisted Selective Oxidation of 1-Phenyl Ethanol in Water Catalyzed by Metal Nanoparticles Immobilized onto Supported Ionic Liquidlike Phases
(ACS Publications, 2015)
The catalytic activity of metal nanometallic particles (MeNPs) immobilized and stabilized onto supported ionic liquidlike phases is evaluated to develop Au- and Pd-based oxidation catalytic systems. Under similar conditions, ...
Green Catalysis-4th International Congress on Green Process Engineering (GPE2014; Sevilla, Spain, April 7-10, 2014)
(Elsevier, 2015-10-15)
This special issue of Catalysis Today entitled Green Catalysis contains selected contributions in the field of Catalysis and Biocatalysis that were presented at the 4th International Congress on Green Process Engineering ...