Anion-Responsive Diguanidinium-Based Chiral Organogelators
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http://dx.doi.org/10.1002/chem.201200943 |
Metadatos
Título
Anion-Responsive Diguanidinium-Based Chiral OrganogelatorsFecha de publicación
2012-10Editor
WileyISSN
0947-6539Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://onlinelibrary.wiley.com/doi/10.1002/chem.201200943/fullPalabras clave / Materias
Resumen
The chiral bicyclic diguanidinium chloride 1 forms gels in aromatic apolar solvents. The gels were characterized at different levels of organization, from the macroscopic to the molecular level by using microscopy, ... [+]
The chiral bicyclic diguanidinium chloride 1 forms gels in aromatic apolar solvents. The gels were characterized at different levels of organization, from the macroscopic to the molecular level by using microscopy, spectroscopy, and powder X-ray diffraction. The dependency on chirality has been highlighted by circular dichroism and electron microscopy. Furthermore, the gel has been shown to be effectively responsive to anionic stimuli, thus allowing the reversible control of the organic-phase gelation in contact with different salted aqueous solutions. [-]
Publicado en
Chemistry - A European Journal, 2012, Vol. 18, num. 41Derechos de acceso
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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