Tuning the Catalytic Efficiency of Palladium Supported Complexes (Pd-NHC-SILLPs): The Cooperative Effect of the Ionic Liquid-Like Groups
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Other documents of the author: Sans, Victor; Gelat, Fabien; Burguete, M. Isabel; Garcia-Verdugo, Eduardo; Luis, Santiago V.
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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http://dx.doi.org/10.1002/masy.201200014 |
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Title
Tuning the Catalytic Efficiency of Palladium Supported Complexes (Pd-NHC-SILLPs): The Cooperative Effect of the Ionic Liquid-Like GroupsAuthor (s)
Date
2012Publisher
WILEY-VCH VerlagISSN
1022-1360; 1521-3900Type
info:eu-repo/semantics/articlePublisher version
http://onlinelibrary.wiley.com/doi/10.1002/masy.201200014/abstractSubject
Abstract
Gel-type Supported Ionic Liquid-like Phases (g-SILLPs) have been employed as medium for the preparation of Palladium carbene (Pd-NHC) complexes. These supported complexes onto ionic liquid-like phases were employed ... [+]
Gel-type Supported Ionic Liquid-like Phases (g-SILLPs) have been employed as medium for the preparation of Palladium carbene (Pd-NHC) complexes. These supported complexes onto ionic liquid-like phases were employed as catalysts for the phosphine-, copper- and amine-free Sonogashira reaction showing excellent activity and selectivity. The loading and nature of the ionic liquid-like moieties have proved to have an effect in the reactivity of the different Pd-NHC-g-SILLPs prepared, with TOF values ranging from 450 to 25000 h. [-]
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Macromolecular Symposia (2012), Vol. 317-318 no. 1Rights
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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