Perceptible Influence of Pd and Pt Heterocyclic Carbene–Pyridyl Complexes in Catalytic Diboration of Cyclic Alkenes
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http://dx.doi.org/10.1002/asia.200900580 |
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Títol
Perceptible Influence of Pd and Pt Heterocyclic Carbene–Pyridyl Complexes in Catalytic Diboration of Cyclic AlkenesData de publicació
2010Editor
Wiley-VCHISSN
1861-4728Cita bibliogràfica
Chemistry – An Asian Journal (2010), 5, 2, p. 261–264Tipus de document
info:eu-repo/semantics/articleVersió de l'editorial
http://onlinelibrary.wiley.com/doi/10.1002/asia.200900580/abstractParaules clau / Matèries
Resum
Bis(catecholato)diboron was added to cyclic alkenes with internal strain to selectively form bis(boryl)cycloalkanes quantitatively in the presence of [Pd(NHC)pyCl2], [Pd(NHC)pyI2], and [Pt(NHC)pyI2] (NHC=N-heterocyclic ... [+]
Bis(catecholato)diboron was added to cyclic alkenes with internal strain to selectively form bis(boryl)cycloalkanes quantitatively in the presence of [Pd(NHC)pyCl2], [Pd(NHC)pyI2], and [Pt(NHC)pyI2] (NHC=N-heterocyclic carbene, py=pyridyl), which have been synthesized and characterized for the first time in this study. [-]
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Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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