Intramolecular oxidation of the alcohol functionalities in hydroxyalkyl-n-heterocyclic carbene complexes of iridium and rhodium
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Altres documents de l'autoria: Benítez Gómez, Miriam; Mas, Elena; Mata Martínez, Jose A; Peris, Eduardo
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Intramolecular oxidation of the alcohol functionalities in hydroxyalkyl-n-heterocyclic carbene complexes of iridium and rhodiumData de publicació
2011-08-04Editor
WILEY-VCH VerlagCita bibliogràfica
Chemistry - A European Journal (2011), 17, 37, p. 10453–10461Tipus de document
info:eu-repo/semantics/articleParaules clau / Matèries
Resum
A series of hydroxyalkyl-functionalized imidazolium salts have been coordinated to Rh and Ir to afford the corresponding MCp*–(NHC) (Cp*=pentamethylcyclopentadienyl) complexes. The reactivity of the new complexes has ... [+]
A series of hydroxyalkyl-functionalized imidazolium salts have been coordinated to Rh and Ir to afford the corresponding MCp*–(NHC) (Cp*=pentamethylcyclopentadienyl) complexes. The reactivity of the new complexes has been studied with special attention to the transformations that deal with the alcohol functionality. The metal-mediated intramolecular transformations allowed the formation of several products that resulted from the oxidation of the alcohols to aldehydes and esters. All the new complexes have been fully characterized, and the crystal structures of the most representative complexes have been resolved. [-]
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