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Enantiomerically pure cyclopentadienyl- and indenyl-functionalized N-heterocyclic carbene complexes of iridium and rhodium
dc.contributor.author | Peris, Eduardo | |
dc.contributor.author | Mata Martínez, Jose A | |
dc.contributor.author | Da Costa, André Pontes | |
dc.contributor.author | Lopes, Rita | |
dc.contributor.author | Cardoso, João M. S. | |
dc.contributor.author | Royo, Beatriz | |
dc.date.accessioned | 2012-10-31T13:40:06Z | |
dc.date.available | 2012-10-31T13:40:06Z | |
dc.date.issued | 2011-08 | |
dc.identifier.issn | 0276-7333 | |
dc.identifier.uri | http://hdl.handle.net/10234/50680 | |
dc.description.abstract | Novel enantiomerically pure cyclopentadienyl- and indenyl-functionalized N-heterocyclic carbene ligands have been prepared by reaction of a chiral imidazole tosylate derivative with the corresponding cyclopentadienyl and indenyl lithium salts. Coordination of the Cp-functionalized NHC ligand to iridium and rhodium allowed the preparation of enantiomerically pure chelating cyclopentadienyl-functionalized Ir(III) and Rh(III) metal complexes. In contrast, the indenyl-functionalized NHC coordinates to iridium in a monodentate fashion, giving an Ir(I)-NHC complex containing a dangling indene group. | ca_CA |
dc.format.extent | 6 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | American Chemical Society | ca_CA |
dc.relation.isPartOf | Organometallics (August 2011), vol. 30, no. 16, 4437–4442 | ca_CA |
dc.rights | © 2011 American Chemical Society | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Enantiomerically pure cyclopentadienyl | ca_CA |
dc.subject | N-heterocyclic carbene ligands | ca_CA |
dc.subject | Organometalloidal compounds | ca_CA |
dc.title | Enantiomerically pure cyclopentadienyl- and indenyl-functionalized N-heterocyclic carbene complexes of iridium and rhodium | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1021/om200523h | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
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