Hierarchical Assembly of CaMoO4 Nano-Octahedrons and Their Photoluminescence Properties
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comunitat-uji-handle2:10234/7013
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http://dx.doi.org/10.1021/jp1082328 |
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Title
Hierarchical Assembly of CaMoO4 Nano-Octahedrons and Their Photoluminescence PropertiesAuthor (s)
Date
2011-03Publisher
ACSISSN
1932-7447Type
info:eu-repo/semantics/articlePublisher version
http://pubs.acs.org/doi/full/10.1021/jp1082328Version
info:eu-repo/semantics/publishedVersionAbstract
Hierarchical assemblies of CaMoO4 (CM) nano-octahedrons were obtained by microwave-assisted hydrothermal synthesis at 120 °C for different times. These structures were structurally, morphologically and optically ... [+]
Hierarchical assemblies of CaMoO4 (CM) nano-octahedrons were obtained by microwave-assisted hydrothermal synthesis at 120 °C for different times. These structures were structurally, morphologically and optically characterized by X-ray diffraction, micro-Raman spectroscopy, field-emission gun scanning electron microscopy, ultraviolet−visible absorption spectroscopy and photoluminescence measurements. First-principle calculations have been carried out to understand the structural and electronic order−disorder effects as a function of the particle/region size. Supercells of different dimensions were constructed to simulate the geometric distortions along both the y and z planes of the scheelite structure. Based on these experimental results and with the help of detailed structural simulations, we were able to model the nature of the order−disorder in this important class of materials and discuss the consequent implications on its physical properties, in particular, the photoluminescence properties of CM nanocrystals. [-]
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Journal of Physical Chemistry C, 2011, 115 (13)Rights
Copyright © 2011 American Chemical Society
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