Gas chromatography-mass spectrometric determination of polybrominated diphenyl ethers in complex fatty matrices from aquaculture activities
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Scholar |
Otros documentos de la autoría: Nácher Mestre, Jaime; Serrano, Roque; Hernandez, Felix; Benedito Palos, Laura; Pérez Sánchez, Jaume
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http://dx.doi.org/10.1016/j.aca.2010.02.015 |
Metadatos
Título
Gas chromatography-mass spectrometric determination of polybrominated diphenyl ethers in complex fatty matrices from aquaculture activitiesAutoría
Fecha de publicación
2010Editor
ElsevierISSN
32670Cita bibliográfica
Analytica Chimica Acta, 664, 2, p. 190-198Tipo de documento
info:eu-repo/semantics/articlePalabras clave / Materias
Resumen
Gas chromatography coupled to mass spectrometry in negative chemical ionization mode (GC-(NCI)MS) has been applied to the quantification and reliable identification of polybrominated diphenyl ethers (PBDEs) in animal ... [+]
Gas chromatography coupled to mass spectrometry in negative chemical ionization mode (GC-(NCI)MS) has been applied to the quantification and reliable identification of polybrominated diphenyl ethers (PBDEs) in animal and vegetable samples from aquaculture activities. Matrices analyzed included fish fillet, fish feed, fish oil and linseed oil, their fat content ranged from 5% to 100%. Solid-phase extraction (SPE) (using Florisil and silica cartridges) and normal-phase high performance liquid chromatography were tested for an efficient clean-up in order to obtain sample extracts free of interfering compounds. Combining sulphuric acid digestion and SPE with Florisil led to the highest efficiency in the elimination of interferences from the extracts. The sample procedure developed, together with the application of GC-(NCI)MS for measurement, led to the satisfactory determination of PBDEs at μgkg<sup>-1</sup> levels in complex aquaculture matrices with high lipid content. The use of a short and thin film-thickness fused-silica capillary column allowed to determine the problematic BDE 209 with satisfactory results. Three m/z ions were acquired for each analyte, which ensured a reliable identification of compounds detected in samples. © 2010 Elsevier B.V. [-]
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