New insights on organosilane oligomerization mechanisms using ESI-MS and 29Si NMR
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Altres documents de l'autoria: Planelles Aragó, José; Vicent Barrera, Cristian; Julian-Lopez, Beatriz; Cordoncillo, Eloisa; Escribano López, Purificación
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Mostra el registre complet de l'elementcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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INVESTIGACIONMetadades
Títol
New insights on organosilane oligomerization mechanisms using ESI-MS and 29Si NMRAutoria
Data de publicació
2009Editor
Royal Society of ChemistryISSN
1144-0546Cita bibliogràfica
PLANELLES ARAGÓ, Jose, et al. New insights on organosilane oligomerization mechanisms using ESI-MS and 29Si NMR. New Journal of Chemistry, 2009, vol. 33, no 5, p. 1100-1108.Tipus de document
info:eu-repo/semantics/articleParaules clau / Matèries
Resum
The use of electrospray ionization mass spectrometry (ESI-MS) in parallel with
29Si and 1H NMR to elucidate the aqueous speciation and temporal evolution of the
organosilane methyldiethoxysilane (MDES) through ... [+]
The use of electrospray ionization mass spectrometry (ESI-MS) in parallel with
29Si and 1H NMR to elucidate the aqueous speciation and temporal evolution of the
organosilane methyldiethoxysilane (MDES) through hydrolysis and condensation processes is
reported here. A suitable methodological approach for the monitoring of the oligomerization of
MDES under different pH conditions has been developed revealing details on the particular
oligomerization mechanism of this organosilane [-]
Publicat a
New Journal of Chemistry, 2009, v. 33, n. 5Drets d'accés
© Royal Society of Chemistry
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