Reduction-triggered Disassembly of Organic Cationic Nanorods Produces a Cysteine Protease Mimic (Miravet et al.)
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Other documents of the author: Navarro Barreda, Diego; Angulo-Pachón, César A.; Galindo, Francisco; Miravet, Juan
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comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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Title
Reduction-triggered Disassembly of Organic Cationic Nanorods Produces a Cysteine Protease Mimic (Miravet et al.)Date
2023Publisher
WileyBibliographic citation
NAVARRO-BARREDA, Diego, et al. Reduction‐triggered disassembly of organic cationic nanorods produces a cysteine protease mimic. Chemistry–A European Journal, 2023, p. e202203764.Type
info:eu-repo/semantics/articleVersion
info:eu-repo/semantics/publishedVersionAbstract
The emergence of catalytic activity associated with
a disassembly process is reported, reminiscent of complex
biological systems. A cystine derivative with pendant
imidazole groups self-assembles into cationic ... [+]
The emergence of catalytic activity associated with
a disassembly process is reported, reminiscent of complex
biological systems. A cystine derivative with pendant
imidazole groups self-assembles into cationic nanorods in the
presence of the cationic surfactants cetylpyridinium chloride
(CPC) or cetyltrimethylammonium bromide (CTAB). Disulfide
reduction triggers nanorod disassembly and the generation
of a simple cysteine protease mimic, which shows a
dramatically improved catalytic efficiency in the hydrolysis of
p-nitrophenyl acetate (PNPA). [-]
Is part of
Chemistry–A European Journal, 2023.Funder Name
Ministerio de Ciencia e Innovación | Unión Europea | Universitat Jaume I
Project code
RTI2018-096748-B-I00 | UJI-B2018-30
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info:eu-repo/semantics/openAccess
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- QUIO_Articles [694]