Chemically Fueled Self-Sorted Hydrogels
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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Title
Chemically Fueled Self-Sorted HydrogelsDate
2022-01-12Publisher
American Chemical SocietyISSN
0002-7863; 1520-5126Bibliographic citation
Singh, N., Lopez-Acosta, A., Formon, G. J., & Hermans, T. M. (2021). Chemically Fueled Self-Sorted Hydrogels. Journal of the American Chemical Society, 144(1), 410-415.Type
info:eu-repo/semantics/articleVersion
info:eu-repo/semantics/acceptedVersionSubject
Abstract
Narcissistic self-sorting in supramolecular assemblies can help to construct materials with more complex hierarchies. Whereas controlled changes in pH or temperature have been used to this extent for two-component ... [+]
Narcissistic self-sorting in supramolecular assemblies can help to construct materials with more complex hierarchies. Whereas controlled changes in pH or temperature have been used to this extent for two-component self-sorted gels, here we show that a chemically fueled approach can provide three-component materials with high precision. The latter materials have interesting mechanical properties, such as enhanced or suppressed stiffness, and intricate multistep gelation kinetics. In addition, we show that we can achieve supramolecular templating, where pre-existing supramolecular fibers first act as templates for growth of a second gelator, after which they can selectively be removed. [-]
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J. Am. Chem. Soc. 2022, 144, 1, 410–415Related data
https://pubs.acs.org/doi/10.1021/jacs.1c10282Funder Name
Marie Curie Individual fellowship EU project | European Union’s Horizon 2020 Research and Innovation Programme under the Marie Skłodowska-Curie grant | Ministère de l’Éducation Nationale de l’Enseignement Supérieur et de la Recherche
Project code
890659-CYCLOTUBES | info:eu-repo/grantAgreement/EC/H2020/812868 | ERC-2017-STG
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Copyright © 2021 American Chemical Society
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