Degradation Analysis of Triple-Cation Perovskite Solar Cells by Electrochemical Impedance Spectroscopy
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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INVESTIGACIONMetadata
Title
Degradation Analysis of Triple-Cation Perovskite Solar Cells by Electrochemical Impedance SpectroscopyAuthor (s)
Date
2022Publisher
American Chemical SocietyISSN
2574-0962Bibliographic citation
Torres, J.; Zarazua, I.; Esparza, D.; Rivas, J. M.; Saliba, M.; Mora-Seró, I.; Turren-Cruz, S.-H.; Abate, A. Degradation Analysis of Triple-Cation Perovskite Solar Cells by Electrochemical Impedance Spectroscopy. ACS Appl. Energy Mater. 2022, 5, 10, 12545–12552, DOI: 10.1021/acsaem.2c02161Type
info:eu-repo/semantics/articlePublisher version
https://pubs.acs.org/doi/full/10.1021/acsaem.2c02161Version
info:eu-repo/semantics/publishedVersionSubject
Abstract
In this work, the electrical properties of different triple-cation compositions with the formula Cs0.05FA1–XMAXPb(I1–XBrX)3 have been analyzed using electrochemical impedance spectroscopy. The perovskite solar cells ... [+]
In this work, the electrical properties of different triple-cation compositions with the formula Cs0.05FA1–XMAXPb(I1–XBrX)3 have been analyzed using electrochemical impedance spectroscopy. The perovskite solar cells were subjected to ambient conditions to compare their results in terms of ambient degradation. Their morphology, optical properties, and photovoltaic performance were characterized. We analyzed the causes and effects of ambient degradation mechanisms on the devices. Electrochemical processes such as ion movement, a combination of radiative recombination and nonradiative recombination, and charge transport were detected. The MA percentage decrease in the composition of triple-cation perovskites, APbX3 produces an improvement in the stability and durability of perovskite solar cells. This enhancement is due to the reduction of the amount of ion vacancies helping to reduce the degradation in the device by avoiding the accumulation of defects. [-]
Is part of
ACS Applied Energy Materials, 2022Funder Name
Ministerio de Economía, Industria y Competitividad
Project code
Ministerio de Economía, Industria y Competitividad.
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info:eu-repo/semantics/openAccess
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