Electrochemical Oscillatory Baffled Reactors Fabricated with Additive Manufacturing for Efficient Continuous-Flow Oxidations
Impact
Scholar |
Other documents of the author: Alvarez, Elena; Romero-Fernandez, Maria; Iglesias, Diego; Martinez Cuenca, Raul; Okafor, Obinna; Delorme, Astrid E.; Lozano, Pedro; Goodridge, Ruth; Paradisi, Francesca; Walsh, Darren; Sans, Victor
Metadata
Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
comunitat-uji-handle4:
INVESTIGACIONMetadata
Title
Electrochemical Oscillatory Baffled Reactors Fabricated with Additive Manufacturing for Efficient Continuous-Flow OxidationsAuthor (s)
Date
2022-02-21Publisher
American Chemical SocietyISSN
2168-0485Bibliographic citation
Alvarez, E.; Romero-Fernandez, M.; Iglesias, D.; Martinez-Cuenca, R.; Okafor, O.; Delorme, A.; Lozano, P.; Goodridge, R.; Paradisi, F.; Walsh, Darren A.; Sans, V. Electrochemical Oscillatory Baffled Reactors Fabricated with Additive Manufacturing for Efficient Continuous-Flow Oxidations. ACS Sustainable Chem. Eng. 2022, 10, 7, 2388–2396. DOI: 10.1021/acssuschemeng.1c06799Type
info:eu-repo/semantics/articlePublisher version
https://pubs.acs.org/doi/10.1021/acssuschemeng.1c06799Version
info:eu-repo/semantics/publishedVersionSubject
Abstract
Electrochemical continuous-flow reactors offer a great opportunity for enhanced and sustainable chemical syntheses. Here, we present a novel application of electrochemical continuous-flow oscillatory baffled reactors ... [+]
Electrochemical continuous-flow reactors offer a great opportunity for enhanced and sustainable chemical syntheses. Here, we present a novel application of electrochemical continuous-flow oscillatory baffled reactors (ECOBRs) that combines advanced mixing features with electrochemical transformations to enable efficient electrochemical oxidations under continuous flow at a millimeter distance between electrodes. Different additive manufacturing techniques have been employed to rapidly fabricate reactors. The electrochemical oxidation of NADH, a very sensitive substrate key for the regeneration of enzymes in biocatalytic transformations, has been employed as a benchmark reaction. The oscillatory conditions improved bulk mixing, facilitating the contact of reagents to electrodes. Under oscillatory conditions, the ECOBR demonstrated improved performance in the electrochemical oxidation of NADH, which is attributed to improved mass transfer associated with the oscillatory regime. [-]
Is part of
ACS Sustainable Chem. Eng. 2022, 10, 7, 2388–2396Funder Name
Generalitat Valenciana | Ministerio de Ciencia, Innovación y Universidades | Fundación SENECA CARM | University Jaume I | European Commission | Biotechnology and Biological Sciences Research Council | EPSRC CDT in Sustainable Chemistry
Funder ID
http://dx.doi.org/10.13039/501100011033
Project code
CIDEGENT/2018/036 | MICIU/ICTI2017-2020/PID2020-119628RB-C33 | MICIU/ICTI2017-2020/RTI2018-098233-B-C21 | 20790/PI/18 | UJI-B2016-52 | info:eu-repo/grantAgreement/EC/H2020/722361 | BB/R021287/1 | EP/L015633/1
Project title or grant
Fabricación avanzada para procesos de cristalización de perovskitas | Nuevos procesos multi-catalíticos verdes basados en la tecnología de los líquidos iónicos. Desde las materias primas sencillas hasta los productos químicos con valor añadido
Rights
Copyright © 2022 The Authors. Published by American Chemical Society
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
This item appears in the folowing collection(s)
- INAM_Articles [521]