Towards highly efficient continuous-flow catalytic carbon dioxide cycloadditions with additively manufactured reactors
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Other documents of the author: Valverde Barquero, David; Porcar Garcia, Raul; Zanatta, Marcileia; Alcalde, Sergio; Altava, Belen; Sans, Victor; Garcia-Verdugo, Eduardo
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Show full item recordcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/160292
comunitat-uji-handle3:10234/160293
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INVESTIGACIONMetadata
Title
Towards highly efficient continuous-flow catalytic carbon dioxide cycloadditions with additively manufactured reactorsAuthor (s)
Date
2022-03-22Publisher
The Royal Society of ChemistryISSN
1463-9270Bibliographic citation
VALVERDE, David, et al. Towards highly efficient continuous-flow catalytic carbon dioxide cycloadditions with additively manufactured reactors. Green Chemistry, 2022.Type
info:eu-repo/semantics/articlePublisher version
https://pubs.rsc.org/en/content/articlelanding/2022/gc/d1gc04593hVersion
info:eu-repo/semantics/acceptedVersionAbstract
Developing efficient and sustainable methodologies to transform CO2 into added-value chemicals is an important strategy for decarbonization in the chemical industry. Here, a new multi-scale approach for the cycloaddition ... [+]
Developing efficient and sustainable methodologies to transform CO2 into added-value chemicals is an important strategy for decarbonization in the chemical industry. Here, a new multi-scale approach for the cycloaddition of CO2 to epoxides is reported, designed by combining the hydrogen bonding ability, metal-free catalysts and supported ionic liquids on polymers. The use of additive manufacturing (AM) techniques allowed the digital design and rapid fabrication of structured architectures for continuous-flow reactors, which offers potential for process optimization. AM generated catalytic reactors showed higher catalytic activity than similar sized packed bed reactors, when normalised to the amount of catalyst and their surface area. The catalytic activity and stability were maintained over a prolonged period of time (300 h) without loss of activity, and it was demonstrated to efficiently transform a range of epoxide substrates. [-]
Is part of
Green Chemistry, 2022Funder Name
Universitat Jaume I | Ministerio de Ciencia e Innovación | Agencia Estatal de Investigación | FEDER | Generalitat Valenciana | European Union's Horizon 2020 | Marie Skłodowska-Curie Individual Fellowships
Project code
UJI-B2019-40 | UJI-B2020-44 | RTI2018-098233-B-C22 | RTI2018-098233-B-C21 | H2020-MSCA-IF-101026335 | CIDEGENT 2018/036
Investigation project
info:eu-repo/grantAgreement/EC/H2020/101026335Rights
http://rightsstatements.org/vocab/InC/1.0/
info:eu-repo/semantics/openAccess
info:eu-repo/semantics/openAccess
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